Thermal radiation often plays a key role in heat transfer between flames and the surrounding environment. Therefore, reliable measurement of flame radiation is indispensable in the study of combustion. While the measurement of radiative flux from flames is straightforward in an open environment, it is challenging to do so in a confined chamber, due to the influence of the walls. Radiation emitted by the walls and the reflection of flame radiation off the walls can interfere with measurements of flame radiation. For wall surfaces that are at high temperature or highly reflective, the error in the flame radiation measurement can be significant. In this paper, a theoretical analysis was carried out to study the contribution of wall emission and wall reflection to the incident radiation measured by radiometers. The results reveal that for a typical lab-scale air-fired flame, the contribution of wall emission and wall reflection to the measured incident radiation can be as high as 55% for a refractory-lined wall and 40% for a water-cooled wall. A convenient approach is proposed to distinguish flame radiation from the measured incident radiation. The approach is based on measurements of surface incident radiation and net radiative heat flux through the wall. The approach can be applied to optically thin systems (most lab-scale and some pilot-scale atmospheric pressure combustion systems) and optically dense systems (typically pressurized large-scale combustion systems). CFD simulations were also performed for two coal-fired combustors, one which represents optically thin and the other optically thick systems, to validate the theoretical model and the approach to estimating flame radiation. Good agreement was observed between CFD results and the theoretical model results, and the proposed approach to estimation of flame radiation was found to have reasonable accuracy. (C) 2017 Elsevier Ltd. All rights reserved.