To increase the photocatalytic reaction rate and make full use of electricity generated by photovoltaics (PV), a water purification system (SOL&PID) with solar and ultraviolet-light emitting diode (UV-LED) powered by a hybrid PV photocatalytic reactor was designed and tested in this paper. The SOL&PID system is based on Solar Water Purification and Renewable Electricity Generation system (SOLWAT). Photovoltaic and photocatalytic performances of SOL&PID system were evaluated in comparison with SOLWAT by the degradation of Acid Red 26 (AR 26) and 4-chlorophenol (4-CP) using suspended TiO2. To assess the directly-coupled performance between PV and UV-LED array, the power consumption percentage of UV-LED array from the maximum output power of PV was analyzed. The results show an adequate coupling between the UV-LED array and the photovoltaics. More than 92% of the maximum output power generated by PV modules is used to drive the LED array. The photocatalytic reaction rate constants in SOL&PID system increase respectively 29-37% and 31-78% during AR 26 and 4-CP experiments, in comparison with SOLWAT system. Besides, the SOL&PID system achieved lower solar module temperature and lower UV-LED pin temperature than the reference systems by the addition of flow channel. (C) 2017 Elsevier Ltd. All rights reserved.