Electrochimica Acta, Vol.226, 89-97, 2017
High-performance CuO/Cu composite current collectors with array-pattern porous structures for lithium-ion batteries
The surface structure and material composition of current collectors significantly affect the electrochemical performances of lithium-ion batteries. This study forms array-pattern blind holes and creates a layer of copper oxide (CuO) on the surface of thin copper plates using the chemical etching method. This copper plate is made into a CuO/Cu composite current collector with array-pattern porous structures for lithium-ion batteries. Using mesocarbon microbead graphite powders as the anode material, this new composite current collector is assembled into CR2032 coin half-cells for electrochemical tests. Batteries with this porous current collector exhibit high reversible discharge capacities of 383.9 mAh g(-1) at 0.5 mA and 374 mAh g(-1) even after 0.2C and 0.5C rate cycles, whereas batteries with a complanate current collector deliver only 309.6 mAh g(-1) and 296.7 mAh g(-1). It is believed that the array-pattern blind holes coupled with the morphological effects of the oatmeal-like CuO significantly enhance the electrochemical performances of batteries in terms of reversible capacity, cycling stability, electrical conductivity and coulombic efficiency. (C) 2016 Elsevier Ltd. All rights reserved.
Keywords:lithium-ion battery;composite current collector;porous structure;copper oxide;equivalent circuit