A urea/carbon nanotubes (CNTs)-decorated metal-organic gel(Fe) was used as self-sacrifice precursors to prepare nano-sized Fe-Fe2O3@ N-doped-C(NC) particles scattered on N-doped CNTs (NCNTs) through pyrolysis at 700 degrees C in N-2. The particles with average size of similar to 10 nm have core@ shell structures with Fe-Fe2O3 cores and NC shells, and the Fe-Fe2O3 cores effectively connect with the NCNT scaffolds via the NC shells. Such a unique structure makes the material a superior oxygen reduction catalyst with an early onset potential (0.92 V), an early half-wave potential (0.72 V), a high current retention (91.7%, after 20,000 s), and good methanol tolerance in an alkaline electrolyte, enabling the catalyst the best among the developed Fe-FeOx oxygen reduction catalysts. (C) 2017 Elsevier Ltd. All rights reserved.