Dimethyl ether (DME) autoignition in turbulent co-flowing jets with preheated air is studied using the one-dimensional turbulence (ODT) model. We investigate the effects of molecular and turbulent transport on the autoignition process at different jet Reynolds numbers and two air preheat conditions. Statistics for the cases considered show that the overall effects of turbulence and molecular transport can serve to delay or accelerate autoignition depending upon where ignition starts, the presence of 2-stage or single stage ignition and the variations in ignition delay times in mixture fraction space. For the higher temperature air preheat cases, the classical view that autoignition is delayed by turbulence is established. For the lower preheat air temperature cases, we show that low-temperature chemistry associated with first-stage ignition can help accelerate the autoignition process and the transition to high-temperature chemistry. This acceleration can reduce the ignition delay time by as much as a factor of 2. Given this work and previous work by the authors based on a different fuel, n-heptane, we find that the ignition delay map based on homogeneous ignition for different mixture fractions can provide a preview of the ignition scenarios for the co-flowing jet configuration regardless of the choice of fuel considered. (C) 2016 The Combustion Institute. Published by Elsevier Inc. All rights reserved.