Journal of Physical Chemistry, Vol.99, No.35, 13291-13300, 1995
Aggregation in Oil-Continuous Water Sodium bis(2-Ethylhexyl)Sulfosuccinate Oil Microemulsions
This paper deals with the aggegation behavior of microemulsion droplets, especially water droplets covered with a monomolecular surfactant layer in oil. In the first part a picture obtained by a number of experimental techniques reported in the literature is reviewed. In the second part we propose a model that describes the aggregation of microemulsion droplets into chainlike aggregates from a thermodynamic point of view. The model is shown to be capable of explaining experimental data measured in a ternary microemulsion using sodium bis(2-ethylhexyl)sulfosuccinate as surfactant quite well.
Keywords:ANGLE NEUTRON-SCATTERING;LIQUID PARTICLE DISPERSIONS;PERCUS-YEVICK APPROXIMATION;KERR EFFECT MEASUREMENTS;REPULSIVE HARD-SPHERES;LIGHT-SCATTERING;MICELLAR INTERACTIONS;MICRO-EMULSIONS;SELF-DIFFUSION;DIELECTRIC-PROPERTIES