아미노실란과 콜로이드 실리카를 이용한 친수성 코팅 도막의 제조

안치용; 이병화; 송기창; Chi-Yong Ah; Byoung-Hwa Lee; Ki Chang Song

Korean Chemical Engineering Research, Vol.55, No.2, 247-252, April, 2017

DOI10.9713/kcer.2017.55.2.247 Export Citation

아미노실란과 콜로이드 실리카를 이용한 친수성 코팅 도막의 제조

Preparation of Hydrophilic Coating Films by using of Aminosilane and Colloidal Silica

안치용, 이병화¹, 송기창 ^†

건양대학교 화공생명학과, 32992 충청남도 논산시 대학로 121
¹대흥화학공업(주) 부설연구소, 17746 경기도 평택시 산단로 64번길 68

Chi-Yong Ah, Byoung-Hwa Lee¹, and Ki Chang Song^†

Department of Chemical and Biochemical Engineering, Konyang University, 121, Daehak-ro, Nonsan-si, Chungnam, 32992, Korea
¹Research Institute of Daehung Chemical Co., Ltd, 68, Sandan-ro 64beon-gil, Pyeongtaek-si, Gyeonggi, 17746, Korea

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초록

실란커플링제인 아미노실란을 15~20 nm의 직경을 갖는 콜로이드 실리카와 반응시킴에 의해 친수성 코팅 용액을 제조하였다. 또한 친수성 코팅 용액을 폴리카보네이트 기재 위에 담금 코팅 시킨 후 120 °C에서 열경화 시킴에 의해 친수성 코팅 도막이 제조되었다. 이 과정 중 아미노실란의 종류 변화가 코팅 도막의 물성에 미치는 영향을 연구하였다. 그 결과 아미노실란으로서 3-aminopropyltriethoxysilane (APTES)을 사용하여 제조된 코팅 도막은 25~44°의 접촉각과 B의 좋지 못한 연필경도를 나타내었다. 반면에 아미노실란으로서 3-aminopropyltrimethoxysilane (APTMS)을 사용하여 제조된 코팅 도막은 26~37°의 접촉각과 2H의 우수한 연필경도를 나타내었다.

Hydrophilic coating solutions were prepared by reacting a silane coupling agent, aminosilane with colloidal silica (15~20 nm in diameter). Hydrophilic coating films were also obtained by depositing the hydrophilic coating solutions on polycarbonate substrates by dip-coating and subsequently by thermal curing at 120 °C. During this process, the effect of types of aminosilane was studied on the properties of coating films. As a result, coating films, prepared with 3-aminopropyltriethoxysilane (APTES) as aminosilane, showed contact angles of 25~44° and a poor pencil hardness of B. On the other hand, coating films, prepared with 3-aminopropyltrimethoxysilane (APTMS) as aminosilane, exhibited contact angles of 26~37° and a good pencil hardness of 2H.

Keywords:Hydrophilic coating solutions;Colloidal Silica;3-Aminopropyltriethoxysilane;3-Aminopropyltrimethoxysilane;Hydrophilic coating films;Pencil hardness

[References]

Cha JK, MS. Dissertation, KAIST, Daejeon, Korea(2000).
Chen GE, Sun L, Xu ZL, Yang H, Hunag HH, Liu YJ, Korean J. Chem. Eng., 32(12), 2492 (2015)
Song KC, Park JK. Kang HU, Kim SH, J. Sol, 27, 53 (2003)
Lim JU, “Coating Method and the Equipment of Anti-Fogging Agent for Agricultural Polymeric Film,” Korea Patent No. 25056(1995).
Lee HS, “Preparation Method of Functional Additives for Agricultural Polymeric Film,” Korea Patent No. 65086(1998).
Lee DI, Jang SH, Song KC, Korean Chem. Eng. Res., 41(6), 768 (2003)
Park JK, Song KC, Kang HU, Kim SH, Korean Chem. Eng. Res., 40(6), 735 (2002)
Lee BH, Kim EK, Lee S, Lim HJ, Lee IP, Korean Chem. Eng. Res., 54(2), 163 (2016)
ASTM D 3359, “Standard Test Methods for Measuring Adhesion by Tape Test,” ASTM International, 927-929(1997).

[Referenced By]

[Related Articles]

[1] Cha JK, MS. Dissertation, KAIST, Daejeon, Korea(2000).

[2] Chen GE, Sun L, Xu ZL, Yang H, Hunag HH, Liu YJ, Korean J. Chem. Eng., 32(12), 2492 (2015)

[3] Song KC, Park JK. Kang HU, Kim SH, J. Sol, 27, 53 (2003)

[4] Lim JU, “Coating Method and the Equipment of Anti-Fogging Agent for Agricultural Polymeric Film,” Korea Patent No. 25056(1995).

[5] Lee HS, “Preparation Method of Functional Additives for Agricultural Polymeric Film,” Korea Patent No. 65086(1998).

[6] Lee DI, Jang SH, Song KC, Korean Chem. Eng. Res., 41(6), 768 (2003)

[7] Park JK, Song KC, Kang HU, Kim SH, Korean Chem. Eng. Res., 40(6), 735 (2002)

[8] Lee BH, Kim EK, Lee S, Lim HJ, Lee IP, Korean Chem. Eng. Res., 54(2), 163 (2016)

[9] ASTM D 3359, “Standard Test Methods for Measuring Adhesion by Tape Test,” ASTM International, 927-929(1997).