화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.25, No.3, 214-221, March, 2017
DOI10.1007/s13233-017-5026-8  Export Citation
Properties in Aqueous Solution of Homo- and Copolymers of Vinylphosphonic Acid Derivatives Obtained by UV-Curing
Lavinia Macarie1, Miloslav Pekar2, Vasile Simulescu1, 2, Nicoleta Plesu1, Smaranda Iliescu1, Gheorghe Ilia1, †, and Milica Tara-Lunga-Mihali1
  • 1Institute of Chemistry Timisoara of Romanian Academy, 24 Mihai Viteazul Blv., 300223 Timisoara, Romania
  • 2Materials Research Centre, Faculty of Chemistry, Brno University of Technology, Purkyňova 118, 61200 Brno, Czech Republic
E-mail:
Vinylphosphonic acid is homopolymerized with dimethylvinylphosphonate by radical polymerization using using UV light and photoinitiator Darocur 4265 (3 wt%). The molar ratio between vinylphosphonic acid and dimethylvinylphosphonate is varied between 1:1 and 4:1, respectively. The obtained homopolymer of vinylphosphonic acid and copolymers are characterized by Fourier transform infrared spectroscopy (FTIR), thermal analysis and size exclusion chromatography - multi angle laser light scattering. The polymerization by UV light is efficient and an average molar mass of 34,200 g/mol is obtained for poly(vinylphosphonic acid) and in the range from 12,700 to 19,120 g/mol for copolymers, which also have a good thermal stability until 320 °C. The polymers structure allows the formation of random coil conformation. The copolymers are tested as inhibitors against corrosion of iron in NaCl aqueous solution, and, as a result, it was shown that these copolymers exhibit promising anticorrosion properties.
Keywords:poly(vinylphosphonic acid);copolymers;anticorrosion;SEC-MALLS;electrochemical impedance
  1. Macarie L, Ilia G, Prog. Polym. Sci, 35, 1078 (2010)
  2. Becker LW, Laboratories B, Inc., US Patent 4446046 (1984).
  3. Neofotistou E, Demadis KD, Int. J. Corros. Scale Inhib., 32, 8 (2014)
  4. Kelland MA, Production Chemicals for the Oil and Gas Industry, 2nd ed. CRC Press, Boca Raton, 2015.
  5. van den Brand J, van Gils S, Beentjes PCJ, Terryn H, Sivel V, de Wit JHW, Prog. Org. Coat., 51, 339 (2004)
  6. Celik SU, Bozkurt A, Macromol. Chem. Phys., 214, 486 (2013)
  7. Bingol B, Jannasch P, in Phosphorus-Based Polymers-From Synthesis to Applications, S. Monge and G. David, Eds., 1st ed., Royal Society of Chemistry, Cambridge, 2014, p 271.
  8. Parvole J, Jannasch P, Macromolecules, 41(11), 3893 (2008)
  9. Rivas BL, Pereira E, Gallegos P, Homper D, Geckeler KE, J. Appl. Polym. Sci., 92(5), 2917 (2004)
  10. Abueva CD, Lee BT, Int. J. Biol. Macromol., 64, 94 (2014)
  11. Kretlow JD, Hacker MC, Klouda L, Ma BB, Mikos AG, Biomacromolecules, 11(3), 797 (2010)
  12. Kim EH, Park SH, Chi SY, Woo HD, Heo Y, Ito Y, Han DK, Nah JW, Son TI, Macromol. Res., 24(2), 99 (2016)
  13. Adusei GO, Deb S, Nicholson JW, Dent. Mater., 21, 491 (2005)
  14. Khouw-Liu VHW, Anstice HM, Pearson GJ, J. Dent., 27, 351 (1999)
  15. Bingol B, Meyer WH, Wagner M, Wegner G, Macromol. Rapid Commun., 27(20), 1719 (2006)
  16. Queffelec C, Petit M, Janvier P, Knight DA, Bujoli B, Chem. Rev., 112(7), 3777 (2012)
  17. Vahabi H, Ferry L, Longuet C, Sonnier R, Negrell-Guirao C, David G, Lopez-Cuesta JM, Eur. Polym. J., 48, 604 (2012)
  18. Milleta F, Auvergne R, Caillol S, David G, Manseri A, Pebere N, Prog. Org. Coat., 77, 285 (2014)
  19. Sato T, Hasegawa M, Seno M, Hirano T, J. Appl. Polym. Sci., 109(6), 3746 (2008)
  20. Pasternak A, Felhosi I, Kerestztes Z, Kalman E, Mater. Sci. Forum, 239, 537 (2007)
  21. Van Alsten JG, Langmuir, 15(22), 7605 (1999)
  22. Paszternak A, Felhosi I, Paszti Z, Kuzmann E, Vertes A, Kalman E, Nyikos L, Electrochim. Acta, 55(3), 804 (2010)
  23. Zimm BH, J. Chem. Phys., 16, 1093 (1948)
  24. Wyatt PJ, Anal. Chim. Acta, 272, 1 (1993)
  25. Simulescu V, Mondek J, Kalina M, Pekar M, Polym. Degrad. Stabil., 111, 257 (2015)
  26. Mondek J, Kalina M, Simulescu V, Pekar M, Polym. Degrad. Stabil., 120, 107 (2015)
  27. Thomas LC, The Identification of Functional Groups in Organophosphorus Compounds, Academic Press, London, 1974.
  28. Stuart B, Infrared Spectroscopy: Fundamentals and Applications, Wiley, New York, 2004.
  29. Mendichi R, in Encyclopedia of Chromatography, Cazes J, Ed., 2nd ed., CRC Press, Boca Raton, Vol. 1, 2005, p 1419.
  30. Han CC, Polymer, 20, 1083 (1979)
  31. Harding SE, in Analytical Ultracentrifugation in Biochemistry and Polymer Science, Harding SE, Rowe AJ, Horton JC, Eds., Royal Society of Chemistry, Cambridge, 1992, p 495.
  32. Hiemenz PC, Timothy LP, Polymer Chemistry, 2nd ed., CRC Press, Boca Raton, 2007.
  33. Kaltbeitzel A, Schauff S, Steininger H, Bingol B, Brunklaus G, Meyer WH, Spiess HW, Solid State Ion., 178(7-10), 469 (2007)
  34. Jiang DD, Yoa Q, McKinney MA, Wilkie CA, Polym. Degrad. Stabil., 63, 423 (1999)
  35. Seemann UB, Dengler JE, Rieger B, Angew. Chem.-Int. Edit., 122, 3567 (2010)
  36. Vahabi H, Ferry L, Longuet C, Sonnier R, Negrell-Guirao C, David G, Lopez-Cuesta JM, Eur. Polym. J., 48, 604 (2012)
  37. Kalman E, Felhosi I, Karman FH, Lukovits I, Telegdi J, Palinkas G, in Corrosion and Environmental Degradation, Series of Materials Science and Technology: A Comprehensive Treatment, Schutze M, Ed., Wiley-VCH, Weinheim, Vol. 1, 2000, Ch. 9.
  38. Demadis KD, Mantzaridis C, Lykoudis P, Ind. Eng. Chem. Res., 45(23), 7795 (2006)
  39. Cao PG, Gu RN, Tian ZQ, Langmuir, 18(20), 7609 (2002)
  40. Bastos AC, Zheludkevich ML, Ferreira MGS, Electrochim. Acta, 26, 47 (2008)
  41. Amar H, Tounsib A, Makayssi A, Derja A, Benzakoura J, Outzourhit A, Corrosion Sci., 49, 2936 (2007)
  42. Amar H, Benzakour J, Derja A, Villemin D, Moreau B, Braisaz T, Appl. Surf. Sci., 252(18), 6162 (2006)