화학공학소재연구정보센터
Powder Technology, Vol.307, 1-9, 2017
Characterizing dispersion and long term stability of concentrated carbon nanotube aqueous suspensions for fabricating ductile cementitious composites
This paper reports a systematic attempt of preparing concentrated aqueous suspensions (up to 03 wt.%) of different types of carbon nanotubes (CNTs) using Pluronic F-127 for developing ductile cementitious composites. Single-walled and multi-walled nanotubes, both pristine and functionalized, were dispersed in water using a short (1 h) and medium energy (80 W) ultrasonication process using pluronic at high concentrations (above critical micelle concentration, 1-5 wt.%) and also using sodium dddecylbenzene sulphonate (SDBS) for comparison purpose. The CNT suspensions were characterized for agglomerate area, particle size, zeta potential, extractability and long-term storage stability for a period over 4 years. The optimum suspensions were used to fabricate cementitious composites and their fracture behavior was characterized. Experimental results suggested that the optimum pluronic concentrations (1% for 0.1% CNT, 5% for 0.2% and 03% CNT, all in weight percent) provided highly homogeneous CNT dispersion with very low area of agglomerates. The best dispersion quality was obtained with f-SWCNT/pluronic system, which provided very low agglomerate area (<0.5%), lower CNT bundle size, good quantity of Well dispersed nanotubes (up to 50%) and excellent long term storage stability. Cementitious composites fabricated using SWCNT and f-SWCNT suspensions showed ductile fracture behavior and improvement in fracture energy up to 164%. (C) 2016 Elsevier B.V. All rights reserved.