화학공학소재연구정보센터
Polymer Bulletin, Vol.74, No.3, 839-856, 2017
Experimental investigation of the effects of a compatibilizing agent on the properties of a recycled poly(ethylene terephthalate)/polypropylene blend
This study deals with the behavior of a recycled polyethylene terephthalate (PET)/polypropylene (PP) blends. The compatibilizing effect has been investigated to examine the recycling feasibility in industrial production. The compatibilizing efficiency of olefinic copolymers containing epoxy groups for a/polypropylene (PET/PP) blends was examined using scanning electron microscopy (SEM), differential scanning calorimetry (DSC), mechanical testing and rheological one. The effect of ethylene-glycidyl methacrylate (E-GMA, 92/8 wt%, Lotader AX8840) and ethylene-methyl acrylate-glycidyl methacrylate (E-MA-GMA, 68/24/8 wt%, Lotader AX8900) copolymers was investigated. The blends of PET/PP/compatibilizer at compositions 80/15/5, 85/11.25/3.75, 90/7.5/2.5 and 95/3.75/1.25 (wt%) were prepared by melt mixing in a single-screw extruder. Test specimens were prepared by compression moulding at processing temperatures of 250 A degrees C. The incorporation of the compatibilizers has a large effect on the dispersion of the PP phase. Moreover, the copolymer was more efficient than the terpolymer. Especially, E-GMA was found to improve the elongation at break of the blends containing 80 % PET.