A series of novel organic-inorganic crosslinked hybrid proton exchange membranes were prepared using sulfonated poly(arylene ether ketone sulfone) polymers containing carboxyl groups (C-SPAEKS), (3-aminopropyl)-triethoxysilane (KH550), and tetraethoxysilane (TEOS). KH550 acted as a "bridge" after reacting with carboxyl and sulfonic groups of C-SPAEKS to form covalent and ionic crosslinked structure between the C-SPAEKS and SiO2 phase. The crosslinked hybrid membranes (C-SPAEKS/K-SiO2) were characterized by FT-IR spectroscopy, TGA, and electrochemistry, etc. The thermal stability, mechanical properties and proton conductivity of the crosslinked hybrid membranes were improved by the presence of both crosslinked structure and inorganic phase. The proton conductivity of C-SPAEKS/K-SiO2-8 was recorded as 0.110 S cm(-1), higher than that of Nafion (R) (0.028 S cm(-1)) at 120 degrees C. Moreover, the methanol permeability of the C-SPAEKS/K-SiO2-8 was measured as 3.86 x 10(-7) cm(2) s(-1), much lower than that of Nafion (R) 117 membranes (29.4 x 10(-7) cm(2) s(-1)) at 25 degrees C. (C) 2016 Elsevier B.V. All rights reserved.