The recovery of iron from the leached solution of red mud with oxalic acid was studied. It was found that the iron in the Fe(C2O4)(3)(3-) formed in the leached solution of red mud with oxalic acid can be effectively separated and recovered by co-precipitation, selective dissolution and re-precipitation. The iron in the leached solution was first precipitated with oxalic acid to form the precipitate containing CaC2O4 center dot 2H(2)O and Fe(OH)(3) by adjusting the pH to about 3.5 with CaCO3. Then the Fe(OH)(3) was selectively dissolved from the precipitate in the solution containing 1 mol/L HC1 and 200 g/L CaCl2 with L/S ratio 4:1 mL/g at room temperature. After filtration, the iron was re-precipitated from the dissolved solution by adjusting the pH to 3.0-4.0 with CaCO3 at 80 degrees C under stirring. The product of Fe2O3 with the purity 98.44% was obtained by adjusting the dissolved solution pH to 3.52 and filtering the precipitate from it, and then calcining the cake at 750 degrees C for 3 h. By adding concentrated hydrochloric acid into the filtrate to adjust its acidity to 1 mol/L HCI, a part of CaCl2 was crystallized from it, and the saturated solution of HCl-CaCl2 was obtained, which was reused in the selective dissolution. The CaC2O4 center dot 2H(2)O remained in the dissolved residue was completely changed into CaSO4 center dot 2H(2)O and H2C2O4 in 3 mol/L H2SO4 with L/S ratio 5:1 mL/g at 60 degrees C stirring for 20 min. By filtering the supernatant immediately, the product of CaSO4.2H(2)O with the purity 99.31% was obtained after washing the cake with dilute sulfuric acid and distilled water, and then the crystal of H2C2O4 center dot 2H(2)O was formed by cooling the filtrate at room temperature. (C) 2016 Elsevier B.V. All rights reserved.