A novel solar cooling system, i.e., the solar absorption-subcooled compression hybrid cooling system (SASCHCS), is a better solution for large-scale buildings with many floors, but the thermodynamic characteristics of the system are not adequately realized. The thermodynamic model of the hybrid system is absent, and the design of the nominal cooling capacity of the absorption subsystem and the volume of the storage tank are not known. Consequently, this paper primarily examined the thermodynamics of SASCHCS. A thermodynamic model of the hybrid system was developed, and the working process and performance of the hybrid system for different nominal cooling capacities of the absorption subsystem and the volumes of storage tanks were analysed in detail. The influence of selected parameters on the performance was discussed. It was found that the performance of the system first increases and subsequently decreases gradually with improvement in the nominal cooling capacity of the absorption subsystem. The appropriate ratio of the nominal cooling capacity of the absorption subsystem to the area of the collector should be 0.148 kW/m(2) to 0.222 kW/m(2). Additionally, the performance of the hybrid system increases first but subsequently decreases gradually with the decrease in volume of the storage tank. An appropriate decrease in the volume of the storage tank is recommended. This paper contributes to a deeper understanding of SASCHCS. (C) 2016 Elsevier B.V. All rights reserved.