The properties of coal tar pitch, which is used as the binder material for carbon anode production, strongly affect the anode properties. Pitches have significant differences in their chemical compositions depending on their origin. In this study, four different coal tar pitches and their blends were studied with the aim of understanding the wettability of a calcined petroleum coke by pitch using the sessile-drop test. In this test, contact angle, which is an indication of wettability, is measured. Contact angles decrease with increasing time, and smaller contact angle means better wettability. The chemical properties of pitches and coke were studied using XPS to investigate their interactions and, consequently, the wetting mechanism. The results showed that blending different pitches influences the wettability. The presence of acidic, basic, and heteroatom containing functional groups in pitch might cause acid-base/condensation reactions when they are blended and, thus, influence the wetting behavior of the pitch blend.