Hydraulic fracturing is the significant technology for exploiting tight resources. Spontaneous water imbibition is an important mechanism governing the process of hydraulic fracturing, and the water imbibition from the fracture into the matrix is an essential factor that affects the reservoir production performance. In this study, imbibition experiments and nuclear magnetic resonance (NMR) testing were combined to analyze fluid flow tight core samples in a pore-scale level. The imbibition experiments were categorized into two systems, the gas/water/rock system and the oil/water/rock system. The NMR measurements were performed at different times for these two systems. The relationship between T-2 relaxation time, pore radius, and pore types was established. Theoretical models describing water imbibition into porous media were used to facilitate the interpretation of the experimental results. The results demonstrate that the volume of imbibed water is large during the early imbibition period and that the imbibition recovery increases rapidly as time proceeds. The volume of imbibed water reaches a constant level at the end of the experiment. The volume of imbibed water in the oil/water/rock experiment is less than that in the gas/water/rock experiment; however, the experiment shows an inverse relation for the duration of the imbibition. For the gas/water/rock system, the water is originally imbibed into micropores and small mesopores present in the natural core samples. There are four types of T2 distributions related to the oil/water/rock imbibition process. Finally, the experimental results indicate the effect of boundary conditions, wettability, temperature, and oil viscosity on water imbibition. The oil recovery due to water imbibition for the oil/water/rock is mainly controlled by the capillary force, gravity force, and characteristic length of the core sample. Water-wet conditions are more preferable for spontaneous imbibition. Through a detailed study of imbibition experiment and NMR testing, significant insight is provided into the fluid flow in the tight porous media.