화학공학소재연구정보센터
Electrochimica Acta, Vol.225, 283-291, 2017
Facile synthesis of flower-like NixCo3-xO4 (0 <= x <= 1.5) microstructures as high-performance electrode materials for supercapacitors
In this reported work, flower-like NixCo3-xO4 (0 <= x <= 1.5) microstructures with different Ni/Co molar ratios were synthesized via a facile solvothermal method followed by calcination. Varying the Ni/Co molar ratio in the solvothermal reaction was found to have a significant influence on the microstructures, surface area and electrochemical performances of the resulting flower-like NixCo3-xO4 products. When the Ni/Co molar ratio was 1: 1, the resulting flower-like Ni1.5Co1.5O4 as an electrode for supercapacitor exhibited a high specific capacity of 502.8C g (1) at 1 A g (1), and the highest capacity retention of 85.7% can be achieved at a high current density of 10 A g (1). Moreover, to further demonstrate the practical application of these materials, an asymmetric supercapacitor was also assembled using the the flower-like Ni1.5Co1.5O4 as the positive electrode and active carbon as the negative electrode. The asymmetric supercapacitor device delivered a remarkable energy density of 47.5 Wh kg (1) at a power density of 855 W kg (1), showing the great promise of these novel materials for potential applications in energy storage. (C) 2016 Elsevier Ltd. All rights reserved.