화학공학소재연구정보센터
Chemical Physics Letters, Vol.667, 211-215, 2017
Thermodynamic properties for the lithium dimer
We present an explicit expression of the vibrational partition function for the improved Manning-Rosen potential energy model. We give analytical expressions for the vibrational mean energy, vibrational specific heat, vibrational free energy, and vibrational entropy for diatomic molecules. The properties of these thermodynamic functions for the a(3)Sigma(+)(u) state of the Li-7(2) molecule are discussed in detail. (C) 2016 Published by Elsevier B.V.