화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.47, 128-140, March, 2017
DOI10.1016/j.jiec.2016.11.024  Export Citation
Novel flexible styrenic elastomer cation-exchange material based on phenyl functionalized polystyrene-butadiene copolymer
Wu Bin Ying, Ji Uk Jang, Min Woo Lee, Taek Sung Hwang, Kyung Jin Lee†, and Bumjae Lee†
  • Department of Fine Chemical Engineering and Applied Chemistry, College of Engineering, Chungnam National University, 99 Daehak-ro (st), Yuseong-gu, Daejeon 305-764, South Korea
E-mail:,
The sulfonated phenyl functionalized polystyrene-butadiene random copolymer was synthesized for application as flexible ion-exchange material. The polymer was prepared through phenyl functionalization via thiol-ene reaction and sulfonation of the base polystyrene-butadiene copolymer with different vinyl contents and phenyl contents. Sulfonation on phenyl functionalized polystyrene-butadiene copolymer was carried out in 1,2-dichloroethane at room temperature using the acetyl sulfonate as the sulfonation agent which was prepared from the reaction of acetyl acetate with sulfuric acid. The sulfonation degrees were adjusted from 7.3 mol% to 24.3 mol% determined by elemental analysis (EA) with great ion exchange capacity (0.60-2.26 meq/g), conductivity (0.47-6.1 mS/cm) and lower water uptake (5.1-12.8 wt.%). These excellent characteristics lead to great potential using as the flexible ion-exchange material.
Keywords:Living anionic polymerization;Styrene-butadiene copolymer;Sulfonation;Ion-exchange resin
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