Synthesis and characterization of polypyrrole doped by cage silsesquioxane with carboxyl groups

Gang Shi; Youxin Che; Luyan Wu; Yao Rong; Caihua Ni

Korean Journal of Chemical Engineering, Vol.34, No.2, 470-475, February, 2017

DOI10.1007/s11814-016-0296-y Export Citation

Synthesis and characterization of polypyrrole doped by cage silsesquioxane with carboxyl groups

Gang Shi, Youxin Che, Luyan Wu, Yao Rong, and Caihua Ni^†

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, 214122 Wuxi, P. R. China

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Cage silsesquioxane with carboxyl groups (POSS-COOH) was successfully synthesized, after which it was added to polypyrrole (PPy) as a dopant to produce the doped PPy (PPy/POSS-COOH) solution. The PPy/POSSCOOH composites were characterized by FTIR (Fourier transformation infrared spectroscopy), SEM (Scanning electron microscopy), TGA (Thermo-gravimetric analysis), CV (Cyclic voltammetry) and RL (Reflection loss). Compared to PPy without POSS-COOH (un-PPy), the conductivity of PPy/POSS-COOH composites could be improved dramatically, reaching up to 0.850 S/cm at 25 °C. Under N2 atmosphere, the residual rate of PPy/POSS-COOH was 68% at 700 °C, 14% higher than the one of un-PPy. Meanwhile, PPy/POSS-COOH had a reflection loss below - 8 dB over 9.35 to 11.20GHz, with a minimum value of - 10.32 dB at 10.54 GHz, thus demonstrating higher microwave absorption than un-PPy. This method may provide a facile route to produce doped conducting polymers with POSS-COOH.

Keywords:Cage Silsesquioxane;Polypyrrole;Thermal Stability;Electrochemical Activity;Microwave-absorbing Ability

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[2] MacDiarmid AG, Angew. Chem.-Int. Edit., 40, 2581 (2001)

[3] Heeger AJ, Angew. Chem.-Int. Edit., 40, 2591 (2001)

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[5] Sonmez G, Sonmez HB, Shen CKE, Wudl F, Adv. Mater., 16(21), 1905 (2004)

[6] Sonmez G, Shen CKF, Rubin Y, Wudl F, Angew. Chem.-Int. Edit., 43, 1498 (2004)

[7] Garnier F, Hajlaoui R, Yassar A, Srivastava P, Science, 265(5179), 1684 (1994)

[8] Wang JZ, Zheng ZH, Li HW, Huck WTS, Sirringhaus H, Nat. Mater., 3(3), 171 (2004)

[9] Drury CJ, Mutsaers CMJ, Hart CM, Matters M, de Leeuw DM, Appl. Phys. Lett., 73, 108 (1998)

[10] Selvakumar M, Pitchumani S, Korean J. Chem. Eng., 27(3), 977 (2010)

[11] Yu G, Zhang C, Heeger AJ, Appl. Phys. Lett., 64, 1540 (1994)

[12] Shi G, Li LQ, Liu LX, Xu DR, Lu N, Hao JY, Huang CY, Chi LF, J. Mater. Chem., 22, 12096 (2012)

[13] Kymissis I, Dimitrakopoulos CD, Purushothaman S, J. Vac. Sci. Technol. B, 20(3), 956 (2002)

[14] Rudge A, Raistrick I, Gottesfeld S, Ferraris JP, Electrochim. Acta, 39(2), 273 (1994)

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[16] Khomenko V, Frackowiak E, Beguin F, Electrochim. Acta, 50(12), 2499 (2005)

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[18] Honarkar H, Barmar M, Barikani M, Shokrollahi P, Korean J. Chem. Eng., 33(1), 319 (2016)

[19] Zhang WA, Muller AHE, Prog. Polym. Sci, 38, 1121 (2013)

[20] Li ZH, Wu DC, Liang YR, Fu RW, Matyjaszewski K, J. Am. Chem. Soc., 136(13), 4805 (2014)

[21] Ni CH, Ni GF, Zhang LP, Mi JQ, Yao BL, Zhu CP, J. Colloid Interface Sci., 362(1), 94 (2011)

[22] Ni CH, Zhu GJ, Zhu CP, Yao BL, Kumar DNT, Colloid Polym. Sci., 288, 1193 (2010)

[23] Wu K, Song L, Hu Y, Lu HD, Kandola BK, Kandare E, Prog. Org. Coat., 65, 490 (2009)

[24] Li GZ, Wang LC, Ni HL, Pittman CU, J. Inorg. Organomet. Polym., 11, 123 (2001)

[25] Opanasenko M, Parker WO, Shamzhy M, Montanari E, Bellettato M, Mazur M, Millini R, Cejka J, J. Am. Chem. Soc., 136(6), 2511 (2014)

[26] Phillips SH, Haddad TS, Tomczak SJ, Curr. opin. Solid State Mat. Sci., 8, 21 (2004)

[27] Ni CH, Wu G, Zhu CP, Yao BL, J. Phys. Chem. C, 114, 13471 (2010)

[28] Li QF, Xu YH, Yoon JS, Chen GX, J. Mater. Sci., 46(7), 2324 (2011)

[29] Ak M, Gacal B, Kiskan B, Yagci Y, Toppare L, Polymer, 49(9), 2202 (2008)

[30] Wang K, Guan X, Chai S, Zou Q, Zhang X, Zhang J, Biosens. Bioelectron., 64, 94 (2015)

[31] Zhang ZP, Liang GZ, Lu TL, J. Appl. Polym. Sci., 103(4), 2608 (2007)

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[33] Dong B, Zhong DY, Chi LF, Fuchs H, Adv. Mater., 17(22), 2736 (2005)

[34] Iqbal R, Khosa MK, Jamal MA, Hamid M, Korean J. Chem. Eng., 32(2), 362 (2015)

[35] Wang ZZ, Bi H, Liu J, Sun T, Wu XL, J. Magn. Magn. Mater., 320, 2132 (2008)