Effect of water on the stability of zinc in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid

Bonita Dilasari; Yeojin Jung; Kyungjung Kwon

Journal of Industrial and Engineering Chemistry, Vol.45, 375-379, January, 2017

DOI10.1016/j.jiec.2016.10.005 Export Citation

Effect of water on the stability of zinc in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid

Bonita Dilasari^{1, 2}, Yeojin Jung^{1, 3}, and Kyungjung Kwon^{1, 3, †}

¹Department of Energy and Mineral Resources Engineering, Sejong University, Seoul 05006, Republic of Korea
²Department of Metallurgical Engineering, Bandung Institute of Technology, Bandung 40132, Indonesia
³, Korea

E-mail:

Ionic liquids are considered as a potential electrolyte for rechargeable zinc-air battery due to nonvolatility, high ionic conductivity, and so on. Electrochemical measurements are conducted to investigate the redox behavior of zinc electrode in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([BMPyr] [NTf2]) ionic liquid and the effect of water in the ionic liquid is also studied. Cyclic voltammetry of zinc electrode in [BMPyr] [NTf2] shows a reversible redox peak, and the presence of water gives significant effects particularly on the cathodic current of zinc electrode. Different surface reaction mechanism on zinc electrode depending on the presence of water in ionic liquid is suggested.

Keywords:Ionic liquid;Zinc-air battery;Redox;Cyclic voltammetry;Water

[References]

Cheng F, Chen J, Chem. Soc. Rev., 41, 2172 (2012)
Rahman MA, Wang XJ, Wen CE, J. Electrochem. Soc., 160(10), A1759 (2013)
Lee JS, Kim ST, Cao R, Choi NS, Lee KT, Cho J, Adv. Eng. Mater., 1, 34 (2011)
Sapkota P, Kim HJ, Ind. Eng. Chem., 15, 445 (2009)
Jorissen L, J. Power Sources, 155(1), 23 (2006)
Lide DR, CRC Handbook of Chemistry and Physics, 81st ed., CRC Press, Boca Raton, 2000.
Kar M, Simons TJ, Forsyth M, MacFarlane DR, Phys. Chem. Chem. Phys., 16, 18658 (2014)
Friesen CA, Buttry DA, Metal.air low temperature ionic liquid cell, U.S.Patent 0285375 A1, Nov 11, 2010.
Rene A, Hauchard D, Lagrost C, Hapiot P, J. Phys. Chem. B, 113(9), 2826 (2009)
Barnes AS, Rogers EI, Streeter I, Aldous L, Hardacre C, Wildgoose GG, Compton RG, J. Phys. Chem. C, 112, 13709 (2008)
Islam MM, Ohsaka TJ, J. Phys. Chem. C, 112, 1269 (2008)
Switzer EE, Zeller R, Chen Q, Sieradzki K, Buttry DA, Friesen C, J. Phys. Chem. C, 117, 8683 (2013)
Izgorodin A, Izgorodina E, MacFarlane DR, Energy Environ. Sci., 5, 9496 (2012)
Simons TJ, Torriero AAJ, Howlett PC, MacFarlane DR, Forsyth M, Electrochem. Commun., 18, 119 (2012)
Xu M, Ivey DG, Xie Z, Qu W, Dy E, Electrochim. Acta, 97, 289 (2013)
Liu Z, El Abedin SZ, Endres F, Electrochim. Acta, 89, 635 (2013)
Liu Z, El Abedin SZ, Endres F, Electrochem. Commun., 58, 46 (2015)
Kar M, Winther-Jensen B, Armand M, Simons TJ, Winther-Jensen O, Forsyth M, MacFarlane DR, Electrochim. Acta, 188, 461 (2016)
Dobryszycki J, Biallozor S, Corrosion Sci., 43, 1309 (2001)
Mouanga M, Bercot P, Rauch JY, Corrosion Sci., 52, 3984 (2010)
Khoo T, Howlett PC, Tsagouria M, MacFarlane DR, Forsyth M, Electrochim. Acta, 58, 583 (2011)
Hayyan M, Mjalli FS, Hashim MA, AlNashef IM, Mei TX, J. Ind. Eng. Chem., 19(1), 106 (2013)
Bozzini B, Griskonis E, Fanigliulo A, Sulciu A, Surf. Coat. Technol., 154, 294 (2002)
Feliu S, Barranco V, Acta Mater., 51, 5413 (2003)
Gabler C, Tomastik C, Brenner J, Pisarova L, Doerra N, Allmaier G, Green Chem., 13, 2869 (2011)
Uhl B, Buchner F, Gabler S, Bozorgchenani M, Behm RJ, Chem. Commun., 50, 8601 (2014)
Gocheva ID, Tanaka I, Doi T, Okada S, Yamaki J, Electrochem. Commun., 11, 1583 (2009)

[1] Cheng F, Chen J, Chem. Soc. Rev., 41, 2172 (2012)

[2] Rahman MA, Wang XJ, Wen CE, J. Electrochem. Soc., 160(10), A1759 (2013)

[3] Lee JS, Kim ST, Cao R, Choi NS, Lee KT, Cho J, Adv. Eng. Mater., 1, 34 (2011)

[4] Sapkota P, Kim HJ, Ind. Eng. Chem., 15, 445 (2009)

[5] Jorissen L, J. Power Sources, 155(1), 23 (2006)

[6] Lide DR, CRC Handbook of Chemistry and Physics, 81st ed., CRC Press, Boca Raton, 2000.

[7] Kar M, Simons TJ, Forsyth M, MacFarlane DR, Phys. Chem. Chem. Phys., 16, 18658 (2014)

[8] Friesen CA, Buttry DA, Metal.air low temperature ionic liquid cell, U.S.Patent 0285375 A1, Nov 11, 2010.

[9] Rene A, Hauchard D, Lagrost C, Hapiot P, J. Phys. Chem. B, 113(9), 2826 (2009)

[10] Barnes AS, Rogers EI, Streeter I, Aldous L, Hardacre C, Wildgoose GG, Compton RG, J. Phys. Chem. C, 112, 13709 (2008)

[11] Islam MM, Ohsaka TJ, J. Phys. Chem. C, 112, 1269 (2008)

[12] Switzer EE, Zeller R, Chen Q, Sieradzki K, Buttry DA, Friesen C, J. Phys. Chem. C, 117, 8683 (2013)

[13] Izgorodin A, Izgorodina E, MacFarlane DR, Energy Environ. Sci., 5, 9496 (2012)

[14] Simons TJ, Torriero AAJ, Howlett PC, MacFarlane DR, Forsyth M, Electrochem. Commun., 18, 119 (2012)

[15] Xu M, Ivey DG, Xie Z, Qu W, Dy E, Electrochim. Acta, 97, 289 (2013)

[16] Liu Z, El Abedin SZ, Endres F, Electrochim. Acta, 89, 635 (2013)

[17] Liu Z, El Abedin SZ, Endres F, Electrochem. Commun., 58, 46 (2015)

[18] Kar M, Winther-Jensen B, Armand M, Simons TJ, Winther-Jensen O, Forsyth M, MacFarlane DR, Electrochim. Acta, 188, 461 (2016)

[19] Dobryszycki J, Biallozor S, Corrosion Sci., 43, 1309 (2001)

[20] Mouanga M, Bercot P, Rauch JY, Corrosion Sci., 52, 3984 (2010)

[21] Khoo T, Howlett PC, Tsagouria M, MacFarlane DR, Forsyth M, Electrochim. Acta, 58, 583 (2011)

[22] Hayyan M, Mjalli FS, Hashim MA, AlNashef IM, Mei TX, J. Ind. Eng. Chem., 19(1), 106 (2013)

[23] Bozzini B, Griskonis E, Fanigliulo A, Sulciu A, Surf. Coat. Technol., 154, 294 (2002)

[24] Feliu S, Barranco V, Acta Mater., 51, 5413 (2003)

[25] Gabler C, Tomastik C, Brenner J, Pisarova L, Doerra N, Allmaier G, Green Chem., 13, 2869 (2011)

[26] Uhl B, Buchner F, Gabler S, Bozorgchenani M, Behm RJ, Chem. Commun., 50, 8601 (2014)

[27] Gocheva ID, Tanaka I, Doi T, Okada S, Yamaki J, Electrochem. Commun., 11, 1583 (2009)