화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.45, 323-333, January, 2017
DOI10.1016/j.jiec.2016.09.044  Export Citation
Fenton-like catalytic oxidation of tetracycline by AC@Fe3O4 as a heterogeneous persulfate activator: Adsorption and degradation studies
Ahmad Jonidi Jafari1, 2, Babak Kakavandi3, 4, †, Nemat Jaafarzadeh3, 5, Roshanak Rezaei Kalantary1, 2, Mehdi Ahmadi3, 5, and Ali Akbar Babaei3, 5
  • 1Research Center for Environmental Health Technology (RCEHT), Iran University of Medical Sciences, Tehran, Iran
  • 2Department of Environmental Health Engineering, Iran University of Medical Sciences, Tehran, Iran
  • 3Department of Environmental Health Engineering, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
  • 4Student Research Committee, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
  • 5Environmental Technologies Research Center, Ahvaz Jundishapur University of Medical Sciences, Ahvaz, Iran
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Fenton-like catalytic degradation of tetracycline (TC) was studied by using ferro-ferric oxide (Fe3O4) nanoparticles coated on activated carbon (AC@Fe3O4) which acts as a peroxidase mimetic and persulfate (PS) as a green oxidant. Adsorption and degradation experiments were carried out in a batch system as functions of pH, PS, catalyst and TC concentrations. Kinetic and pathway of TC degradation by AC@Fe3O4/PS system was also investigated. Under the optimum conditions, the removal efficiency of TC and total organic carbon (TOC) were 99.8 and 50.6%, respectively. AC@Fe3O4 retained its activity and degradation efficiency remained even after five concessive cycles of use.
Keywords:Fe3O4 nanoparticles;Heterogeneous catalyst;Fenton-like degradation;Tetracycline;Activator persulfate
  1. Hou LW, Wang LG, Royer S, Zhang H, J. Hazard. Mater., 302, 458 (2016)
  2. Weng CH, Huang V, J. Ind. Eng. Chem., 28, 153 (2015)
  3. Kakavandi B, Takdastan A, Jaafarzadeh N, Azizi M, Mirzaei A, Azari A, J. Photochem. Photobiol. A-Chem., 314, 178 (2015)
  4. Stoyanova M, Slavova I, Christoskova S, Ivanova V, Appl. Catal. A: Gen., 476, 121 (2014)
  5. Qin W, Fang G, Wang Y, Wu T, Zhu C, Zhou D, Chemosphere, 148, 68 (2016)
  6. Liu J, Zhao ZW, Shao PH, Cui FY, Chem. Eng. J., 262, 854 (2015)
  7. Tang DD, Zhang GK, Guo S, J. Colloid Interface Sci., 454, 44 (2015)
  8. Ren YM, Lin LQ, Ma J, Yang J, Feng J, Fan ZJ, Appl. Catal. B: Environ., 165, 572 (2015)
  9. Yan JC, Lei M, Zhu LH, Anjum MN, Zou J, Tang HQ, J. Hazard. Mater., 186(2-3), 1398 (2011)
  10. Sharma J, Mishra IM, Dionysiou DD, Kumar V, Chem. Eng. J., 276, 193 (2015)
  11. Bayat M, Sohrabi M, Royaee SJ, J. Ind. Eng. Chem., 18(3), 957 (2012)
  12. Li RC, Jin XY, Megharaj M, Naidu R, Chen ZL, Chem. Eng. J., 264, 587 (2015)
  13. Usman M, Faure P, Ruby C, Hanna K, Chemosphere, 87, 234 (2012)
  14. Tang XJ, Hashmi MZ, Zeng B, Yang JW, Shen CF, Chem. Eng. J., 279, 673 (2015)
  15. Nezamzadeh-Ejhieh A, Ghanbari-Mobarakeh Z, J. Ind. Eng. Chem., 21, 668 (2015)
  16. Jaafarzadeh N, Kakavandi B, Takdastan A, Kalantary RR, Azizi M, Jorfi S, RSC Adv., 5, 84718 (2015)
  17. Iglesias O, Dios MAFD, Tavares T, Sanroman MA, Pazos M, J. Ind. Eng. Chem., 27, 276 (2015)
  18. American Society for Testing and Material (ASTM) (2012).
  19. Apha A, Standard Methods for the Examination of Water and Wastewater, American Public Health Association, Washington, DC, 2016, pp. 94 Part 8000.
  20. Kakavandi B, Babaei AA, RSC Adv., 6, 84999 (2016)
  21. Kakavandi B, Kalantary RR, Jafari AJ, Nasseri S, Ameri A, Esrafili A, Azari A, Clean-Soil Air Water, 43, 1157 (2015)
  22. Jafari AJ, Kakavandi B, Kalantary RR, Gharibi H, Asadi A, Azari A, Babaei AA, Takdastan A, Korean J. Chem. Eng., 33(10), 2878 (2016)
  23. Lin YX, Xu S, Jia L, Chem. Eng. J., 225, 679 (2013)
  24. Kakavandi B, Jahangiri-Rad M, Rafiee M, Esfahani AR, Babaei AA, Microporous Mesoporous Mater., 231, 192 (2016)
  25. Esfahani AR, Firouzi AF, Sayyad G, Kiasat A, Alidokht L, Khataee AR, Res. Chem. Intermed., 40, 431 (2014)
  26. Tan CQ, Gao NY, Chu WH, Li C, Templeton MR, Sep. Purif. Technol., 95, 44 (2012)
  27. Long AH, Lei Y, Zhang H, Ind. Eng. Chem. Res., 53(3), 1033 (2014)
  28. Xu XR, Li XZ, Sep. Purif. Technol., 72(1), 105 (2010)
  29. Weng CH, Tsai KL, Ultrason. Sonochem., 29, 11 (2016)
  30. Wang S, Zhou N, Ultrason. Sonochem., 29, 156 (2016)
  31. Khataee A, Salahpour F, Fathinia M, Seyyedi B, Vahid B, J. Ind. Eng. Chem., 26, 129 (2015)
  32. Zhao L, Hou H, Fujii A, Hosomi M, Li F, Environ. Sci. Pollut. Res., 21, 7457 (2014)
  33. Organization WH, Guidelines for Drinking-Water Quality: First Addendum, vol. 1, World Health Organization, 2006 Recommendations.