Journal of the American Ceramic Society, Vol.99, No.9, 3060-3066, 2016
Densification Behavior, Phase Transition, and Preferred Orientation of Hot-Pressed ZnS Ceramics from Precipitated Nanopowders
In this study, transparent ZnS ceramics were hot pressed from precipitated wurtzite nanopowders. Influences of sintering temperature on wurtzite-to-sphalerite phase transition and densification behavior have been investigated. Maximum sphalerite phase content and highest densification were simultaneously obtained in the sample hot pressed at 900 degrees C with uniaxial pressure of 250 MPa for 2 h, which accounts for the highest transmittance above 55% and 70% in the range 2-5 mu m and 5-13 mu m, respectively. Preferred orientation of wurtzite grains in [002] direction paralleled to the press direction was also observed, which is supposed to be benefit to transmittance by reducing birefraction and second-phase scattering. Furthermore, second-phase scattering caused by wurtzite grains has been investigated. It is found that fine grains are conducive to hot-pressed ZnS ceramics with high transmittance, especially in the short-wavelength range.
Keywords:phase transformations;densification;orientation;optical materials/properties;transparent ceramics