Astronomical IR emission spectra form the basis for the now widely accepted abundant presence of polycyclic aromatic hydrocarbons (PAHs) in inter- and circumstellar environments. A small but consistent frequency mismatch is found between the astronomically observed emission band near 6.2 mu m and typical CC-stretching vibrations of PAHs measured in laboratory spectra near 6.3-6.4 mu m. The shift of the band has been tentatively attributed to a variety of effects, among which the inclusion of heteroatoms, in particular nitrogen, in the PAH skeleton (PANH) as well as to metal ion binding to the PAH molecule. Here we experimentally investigate the combined effect of nitrogen-inclusion and metal ion binding on the IR spectra. In particular, infrared multiple-photon dissociation (IRMPD) spectra are recorded for coordination complexes of Cu+ with one or two quinoline, isoquinoline, and acridine ligands; complexes of the form Cu (PANH) (MeCN), where the MeCN (acetonitrile) ligand acts as a relatively weakly bound "messenger" are also recorded to qualitatively verify that potential frequency shifts induced by IRMPD are minimal. The experimental IR spectra document the accuracy of IR spectral predictions by density functional theory calculations performed at the B3LYP/6-311+G(2df,2p) level and confirm that a sigma-bond is formed between the copper ion and the exoskeletal N atom. The experimental spectra suggest that the CNC stretching mode undergoes a small red shift of up to 20 cm(-1), with respect to the band position in the uncomplexed PANH molecule, away from the 6.2 mu m interstellar position.