Harvested forest residues are usually considered a fire hazards and used as "hog-fuel" which results in air pollution. In this study, the biorefinery lignin stream obtained after wet explosion pretreatment and enzymatic hydrolysis of forestry residues of Douglas Fir (FS-10) was characterized and further wet oxidized under alkaline conditions. The studies indicated that at 10% solids, 11.7 wt% alkali and 15 min residence time, maximum yields were obtained for glucose (12.9 wt%), vanillin (0.4 wt%) at 230 degrees C; formic acid (11.6 wt%) at 250 degrees C; acetic acid (10.7 wt%), hydroxybenzaldehyde (0.2 wt%), syringaldehyde (0.13 wt%) at 280 degrees C; and lactic acid (12.4 wt%) at 300 degrees C. FTIR analysis of the solid residue after wet oxidation showed that the aromatic skeletal vibrations relating to lignin compounds increased with temperature indicating that higher severity could result in increased lignin oxidation products. The results obtained, as part of the study, is significant for understanding and optimizing processes for producing high-value bioproducts from forestry residues. (C) 2016 Elsevier Ltd. All rights reserved.