Rapid adsorption of cobalt (II) by 3-aminopropyltriethoxysilane modified halloysite nanotubes

Xin Wang; Yuantao Chen; Wei Zhang; Wenfang He; Jian Wang; Biqing Chen

Korean Journal of Chemical Engineering, Vol.33, No.12, 3504-3510, December, 2016

DOI10.1007/s11814-015-0260-2 Export Citation

Rapid adsorption of cobalt (II) by 3-aminopropyltriethoxysilane modified halloysite nanotubes

Xin Wang, Yuantao Chen^†, Wei Zhang, Wenfang He, Jian Wang, and Biqing Chen

Department of Chemistry, Qinghai Normal University, Xining 810008, P. R. China

E-mail:

The adsorption of cobalt (II) by 3-aminopropyltriethoxysilane (APTS) modified halloysite nanotubes (HNTs) was studied. The modified halloysite was characterized by Fourier transform infrared spectroscopy (FT-IR), XRay diffraction (XRD) and thermogravimetry (TG). In addition, a batch method was used to study the adsorption behavior and the mechanism of removal Co (II) by modified HNTs; the effective factors influencing the adsorption process including adsorbent concentration, contact time, initial pH, temperature and the initial concentration of Co (II) have been investigated. The results showed that the APTS was successfully grafted on the HNTs surface. The modified HNTs exhibited rapid adsorption speed, which reached the adsorption equilibrium within 30 min. The adsorption capacity of the adsorbent increased significantly with the increase of pH. The adsorption data of Co (II) on the modified HNTs are well consistent with the Langmuir model and the pseudo-second-order kinetic model.

Keywords:Halloysite Nanotube;3-Aminopropyltriethoxysilane;Modification;Cobalt;Adsorption

[References]

Qadeer R, J. Radioanal. Nucl. Chem., 295, 2021 (2013)
Hete YV, Gholse SB, Khope RU, J. Mater. Sci. Eng. Part B, 1, 117 (2011)
Du H, Central South University, Chang Sha, Hu Nan provice in China (2013).
Puma GL, Bono A, Krishnaiah D, Collin JG, J. Hazard. Mater., 157(2-3), 209 (2008)
Tofighy MA, Mohammadi T, Korean J. Chem. Eng., 32(2), 292 (2015)
Khorzughy SH, Eslamkish T, Ardejani FD, Heydartaemeh MR, Korean J. Chem. Eng., 32(1), 88 (2015)
Oh S, Kim DS, Environ. Sci. Health Part B, 49, 710 (2014)
Fang YT, Liu T, Zhang ZC, Gao XN, Renew. Energy, 63, 755 (2014)
Luo P, Zhang JS, Zhang B, Wang JH, Zhao YF, Liu JD, Ind. Eng. Chem. Res., 50(17), 10246 (2011)
Du Y, Zheng P, Korean J. Chem. Eng., 31(11), 2051 (2014)
Luo P, Zhang B, Zhao Y, Wang J, Zhang H, Liu J, Korean J. Chem. Eng., 28(3), 800 (2011)
Hu PW, Yang HM, Phys. Chem. Miner., 39, 339 (2012)
Du ML, Guo BC, Jia DM, Polym. Int., 59, 574 (2010)
Hughes AD, King MR, Langmuir, 26(14), 12155 (2010)
Lvov YM, Shchukin DG, Price RR, ACS Nano, 2, 814 (2008)
Wang L, Chen JL, Ge L, Zhu ZH, Rudolph V, Energy Fuels, 25(8), 3408 (2011)
Zhai R, Zhang B, Liu L, Xie YD, Zhang HQ, Liu JD, Catal. Commun., 12, 259 (2010)
Zhao MF, Liu P, Microporous Mesoporous Mater., 112, 419 (2008)
Luo P, Zhao YF, Zhang B, Liu JD, Yang Y, Liu JF, Water Res., 44, 1489 (2010)
Wang JH, Zhang XA, Zhang B, Zhao YF, Zhai R, Liu JD, Chen RF, Desalination, 259(1-3), 22 (2010)
Du Y, Zheng P, Korean J. Chem. Eng., 31(11), 2051 (2014)
Tang YH, Deng SQ, Ye L, Yang C, Yu Q, Zhang JN, Zhao CB, Compos. Pt. A-Appl. Sci. Manuf., 42, 345 (2011)
Pasbakhsh P, Ismail H, Fauzi MA, Bakar AA, Appl. Clay Sci., 48, 405 (2010)
Guo BC, Lei YD, Chen F, Liu XL, Du ML, Jia DM, Appl. Surf. Sci., 255(5), 2715 (2008)
Rooj S, Das A, Thakur V, Mahaling RN, Bhowmick AK, Heinrich G, Mater. Des., 31, 2151 (2010)
Pasbakhsh P, Ismail H, Fauzi MNA, Bakar AA, Appl. Clay Sci., 48, 3 (2010)
Dong Y, Chaudhary D, Haroosh H, Bickford T, J. Mater. Sci., 46(18), 6148 (2011)
Haroosh HJ, Yu D, Chaudhary DS, Ingram G, Yusa S, Appl. Phys. A-Mater. Sci. Process., 110, 439 (2013)
Lun HL, Ouyang J, Yang H, Appl. Clay Sci., 4, 44198 (2014)
Guo BC, Lei YD, Chen F, Liu XL, Du ML, Jia DM, Appl. Surf. Sci., 255, 5 (2008)
Wang DL, Yang J, Tan MJ, Li YH, Li WL, Package. J., 2, 19 (2010)
Yuan P, Southon PD, Liu ZW, Green MER, Hook JM, Antill SJ, Kepert CJ, J. Phys. Chem. C, 112, 15748 (2008)
Hu CL, Chen YT, Zhang W, Wang PP, Wang J, Acta Sci. Circumst., 35, 2814 (2014)
Hu CL, Chen YT, Zhang W, Xiao J, Chi YL, He WF, Chem. Ind. Eng. Prog., 33, 2412 (2014)
Li ZM, Chen TF, Yi FC, J. Southwest Univ., 22, 35 (2007)
Zhang ZJ, Deng Y, Zhao ZY, Lv GC, Environ. Sci. Technol., 36, 168 (2013)
Che JX, Kuai LP, Wang XP, Ind. Water Treat., 31, 70 (2011)
Liu Y, Gao J, Li CX, Pan JM, Yan YS, Xie JM, Chin. J. Chem., 28, 552 (2010)
Chen CL, Li XL, Zhao DL, Tan XL, Wang XK, Colloids Surf. A: Physicochem. Eng. Asp., 302, 450 (2007)
Erdem E, Karapinar N, Donat R, J. Colloid Interface Sci., 280, 312 (2004)
Vijayaraghavan K, Thilakavathi M, Palanivelu K, Velan M, Environ. Technol., 26, 274 (2005)
Smiciklas I, Dimovic S, Plecas I, Mitric M, Water Res., 40, 2272 (2006)

[1] Qadeer R, J. Radioanal. Nucl. Chem., 295, 2021 (2013)

[2] Hete YV, Gholse SB, Khope RU, J. Mater. Sci. Eng. Part B, 1, 117 (2011)

[3] Du H, Central South University, Chang Sha, Hu Nan provice in China (2013).

[4] Puma GL, Bono A, Krishnaiah D, Collin JG, J. Hazard. Mater., 157(2-3), 209 (2008)

[5] Tofighy MA, Mohammadi T, Korean J. Chem. Eng., 32(2), 292 (2015)

[6] Khorzughy SH, Eslamkish T, Ardejani FD, Heydartaemeh MR, Korean J. Chem. Eng., 32(1), 88 (2015)

[7] Oh S, Kim DS, Environ. Sci. Health Part B, 49, 710 (2014)

[8] Fang YT, Liu T, Zhang ZC, Gao XN, Renew. Energy, 63, 755 (2014)

[9] Luo P, Zhang JS, Zhang B, Wang JH, Zhao YF, Liu JD, Ind. Eng. Chem. Res., 50(17), 10246 (2011)

[10] Du Y, Zheng P, Korean J. Chem. Eng., 31(11), 2051 (2014)

[11] Luo P, Zhang B, Zhao Y, Wang J, Zhang H, Liu J, Korean J. Chem. Eng., 28(3), 800 (2011)

[12] Hu PW, Yang HM, Phys. Chem. Miner., 39, 339 (2012)

[13] Du ML, Guo BC, Jia DM, Polym. Int., 59, 574 (2010)

[14] Hughes AD, King MR, Langmuir, 26(14), 12155 (2010)

[15] Lvov YM, Shchukin DG, Price RR, ACS Nano, 2, 814 (2008)

[16] Wang L, Chen JL, Ge L, Zhu ZH, Rudolph V, Energy Fuels, 25(8), 3408 (2011)

[17] Zhai R, Zhang B, Liu L, Xie YD, Zhang HQ, Liu JD, Catal. Commun., 12, 259 (2010)

[18] Zhao MF, Liu P, Microporous Mesoporous Mater., 112, 419 (2008)

[19] Luo P, Zhao YF, Zhang B, Liu JD, Yang Y, Liu JF, Water Res., 44, 1489 (2010)

[20] Wang JH, Zhang XA, Zhang B, Zhao YF, Zhai R, Liu JD, Chen RF, Desalination, 259(1-3), 22 (2010)

[21] Du Y, Zheng P, Korean J. Chem. Eng., 31(11), 2051 (2014)

[22] Tang YH, Deng SQ, Ye L, Yang C, Yu Q, Zhang JN, Zhao CB, Compos. Pt. A-Appl. Sci. Manuf., 42, 345 (2011)

[23] Pasbakhsh P, Ismail H, Fauzi MA, Bakar AA, Appl. Clay Sci., 48, 405 (2010)

[24] Guo BC, Lei YD, Chen F, Liu XL, Du ML, Jia DM, Appl. Surf. Sci., 255(5), 2715 (2008)

[25] Rooj S, Das A, Thakur V, Mahaling RN, Bhowmick AK, Heinrich G, Mater. Des., 31, 2151 (2010)

[26] Pasbakhsh P, Ismail H, Fauzi MNA, Bakar AA, Appl. Clay Sci., 48, 3 (2010)

[27] Dong Y, Chaudhary D, Haroosh H, Bickford T, J. Mater. Sci., 46(18), 6148 (2011)

[28] Haroosh HJ, Yu D, Chaudhary DS, Ingram G, Yusa S, Appl. Phys. A-Mater. Sci. Process., 110, 439 (2013)

[29] Lun HL, Ouyang J, Yang H, Appl. Clay Sci., 4, 44198 (2014)

[30] Guo BC, Lei YD, Chen F, Liu XL, Du ML, Jia DM, Appl. Surf. Sci., 255, 5 (2008)

[31] Wang DL, Yang J, Tan MJ, Li YH, Li WL, Package. J., 2, 19 (2010)

[32] Yuan P, Southon PD, Liu ZW, Green MER, Hook JM, Antill SJ, Kepert CJ, J. Phys. Chem. C, 112, 15748 (2008)

[33] Hu CL, Chen YT, Zhang W, Wang PP, Wang J, Acta Sci. Circumst., 35, 2814 (2014)

[34] Hu CL, Chen YT, Zhang W, Xiao J, Chi YL, He WF, Chem. Ind. Eng. Prog., 33, 2412 (2014)

[35] Li ZM, Chen TF, Yi FC, J. Southwest Univ., 22, 35 (2007)

[36] Zhang ZJ, Deng Y, Zhao ZY, Lv GC, Environ. Sci. Technol., 36, 168 (2013)

[37] Che JX, Kuai LP, Wang XP, Ind. Water Treat., 31, 70 (2011)

[38] Liu Y, Gao J, Li CX, Pan JM, Yan YS, Xie JM, Chin. J. Chem., 28, 552 (2010)

[39] Chen CL, Li XL, Zhao DL, Tan XL, Wang XK, Colloids Surf. A: Physicochem. Eng. Asp., 302, 450 (2007)

[40] Erdem E, Karapinar N, Donat R, J. Colloid Interface Sci., 280, 312 (2004)

[41] Vijayaraghavan K, Thilakavathi M, Palanivelu K, Velan M, Environ. Technol., 26, 274 (2005)

[42] Smiciklas I, Dimovic S, Plecas I, Mitric M, Water Res., 40, 2272 (2006)