화학공학소재연구정보센터
Korea-Australia Rheology Journal, Vol.28, No.4, 267-273, November, 2016
Analysis of fractal aggregates in a colloidal suspension of carbon black from its sedimentation and viscosity behavior
E-mail:
Colloidal aggregates in a suspension of carbon black particles are characterized by fractal dimension and their shear dependence. Carbon black particles of 100 nm in diameter are dispersed in Newtonian ethylene glycol with particle volume fraction φ ranging from 0.01 to 0.1. Microstructure of the aggregates is estimated by hydrodynamic transport properties such as average settling velocity and shear viscosity. Scaling analysis is conducted to correlate the hydrodynamic transport properties and the fractal dimension df. The fractal dimension is estimated to be 2.21 from the scaling relation between the settling velocity and the particle volume fraction for φ = 0.01-0.05. The shear viscosity results show shear-thinning behavior of the colloidal suspension. The intrinsic viscosity for the colloidal aggregates is obtained from the data of shear viscosity versus particle concentration. A scaling relation between the intrinsic viscosity and the shear rate gives df = 1.93 at m = 1/3, where m is the exponent defined by a scaling relation between aggregate radius Rg and shear rate S, Rg ∝S-m. Another scaling relation using yield stress data presents df = 1.94, which is nearly equivalent to 1.93 from that by the intrinsic viscosity but quite lower than that from the settling velocity. This discrepancy of the fractal dimension can be attributed to growth or restructuring of the colloidal aggregates by the hydrodynamic stress during long-time settling process.
  1. Allain C, Cloitre M, Parisse F, J. Colloid Interface Sci., 178(2), 411 (1996)
  2. Allain C, Cloitre M, Wafra M, Phys. Rev. Lett., 74, 1478 (1995)
  3. Buscall R, Mills PD, Goodwin JW, Lawson D, J. Chem. Soc.-Perkin Trans. 1, 84, 4249 (1988)
  4. Casson N, 1959, A flow equation for pigment-oil suspensions of the printing ink type, In: Mill CC, eds., Rheology of Disperse Systems, Pergamon Press, Oxford, 84-104.
  5. Cho J, Koo S, J. Ind. Eng. Chem., 27, 218 (2015)
  6. Forrest SR, Witten TA, J. Phys. A-Math. Gen., 12, L109 (1979)
  7. Jullien R, Botet R, 1987, Aggregation and Fractal Aggregates, World Scientific, Singapore.
  8. Krieger IM, Dougherty TJ, Trans. Soc. Rheol., 3, 137 (1959)
  9. Lee B, Koo S, Powder Technol., 266, 16 (2014)
  10. Lin MY, Lindsay HM, Weitz DA, Klein R, Ball RC, Meakin P, J. Phys. Condens. Matter, 2, 3093 (1990)
  11. Lin MY, Lindsay HM, Weitz DA, Ball RC, Klein R, Meakin P, Phys. Rev., A, 41, 2005 (1990)
  12. Lin MY, Lindsay HM, Weitz DA, Ball RC, Klein R, Meakin P, Nature, 339, 360 (1989)
  13. Mewis J, Wagner NJ, 2012, Colloidal Suspension Rheology, Cambridge Press, Cambridge.
  14. Mokhtari T, Chakrabarti A, Sorensen CM, Cheng CY, Vigil D, J. Colloid Interface Sci., 327(1), 216 (2008)
  15. Oles V, J. Colloid Interface Sci., 154, 351 (1992)
  16. Potanin AA, J. Colloid Interface Sci., 157, 399 (1993)
  17. Potanin AA, Derooij R, Vandenende D, Mellema J, J. Chem. Phys., 102(14), 5845 (1995)
  18. Russel WB, Sperry PR, Prog. Org. Coat., 23, 305 (1994)
  19. Shih WY, Shih WH, Aksay IA, J. Am. Ceram. Soc., 82, 616 (1999)
  20. Smith TL, Bruce CA, J. Colloid Interface Sci., 72, 13 (1979)
  21. Smoluchowski MV, Z. Phys., 17, 557 (1916)
  22. Snabre P, Mills P, J. Phys. III France, 6, 1811 (1996)
  23. Sonntag RC, Russel WB, J. Colloid Interface Sci., 113, 399 (1986)
  24. Sorensen CM, Kim W, Fry D, Shi D, Chakrabarti A, Langmuir, 19(18), 7560 (2003)
  25. Tang P, Greenwood J, Raper JA, J. Colloid Interface Sci., 247(1), 210 (2002)