화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.43, 177-184, November, 2016
Fabrication of platinum nano-crystallites decorated TiO2 nano-tube array photoelectrode and its enhanced photoelectrocatlytic performance for degradation of aspirin and mechanism
E-mail:,
In this study, Pt NCs/TiO2 NTAs photoelectrode was fabricated through anodization process, followed by recycle pulse electrodeposition strategy. Subsequently, physicochemical properties of the resulting samples were studied systematically. Results indicated that Pt NCs/TiO2 NTAs photoelectrode exhibited intense light absorbance both in the UV and visible region, high transient photocurrent density of 0.089 mA cm-2 and open circuit potential of -0.275 V cm-2. In addition, 98.3% of aspirin could be eliminated within 4 h Xenon illumination with the help of +0.4 V potential. Furthermore, it can be concluded that two tentative pathways for PEC degradation of aspirin were proposed and confirmed.
  1. Benitez FJ, Acero JL, Real FJ, Roldan G, Rodriguez E, Ozone-Sci. Eng., 35, 263 (2013)
  2. Delgado LF, Charles P, Glucina K, Morlay C, Water Res., 46, 6196 (2012)
  3. Murray KE, Thomas SM, Bodour AA, Environ. Pollut., 158, 3462 (2010)
  4. Overturf MD, Anderson JC, Pandelides Z, Beyger L, Holdway DA, Crit. Rev. Toxicol., 45, 469 (2015)
  5. Agunbiade FO, Moodley B, Environ. Toxicol. Chem., 35, 36 (2016)
  6. Vieno NM, Harkki H, Tuhkanen T, Kronberg L, Environ. Sci. Technol., 41, 5077 (2007)
  7. Li D, Jia JL, Zheng T, Cheng XW, Yu XJ, Appl. Catal. B: Environ., 188, 259 (2016)
  8. Linsebigler AL, Lu GQ, Yates JT, Chem. Rev., 95(3), 735 (1995)
  9. Joung SK, Amemiya T, Murabayashi M, Itoh K, Chem.-Eur. J., 12, 5526 (2006)
  10. Zhu K, Neale NR, Miedaner A, Frank AJ, Nano Lett., 7, 69 (2007)
  11. Shin K, Seok S, Im SH, Park JH, Chem. Commun., 46, 2385 (2010)
  12. Cheng XW, Liu HL, Chen QH, Li JJ, Yu XJ, J. Alloy. Compd., 566, 120 (2013)
  13. Bao ZQ, Xie HX, Rao J, Chen L, Wei Y, Li HF, Zhou XF, Mater. Lett., 124, 158 (2014)
  14. Cheng XW, Liu HL, Chen QH, Li JJ, Wang P, J. Hazard. Mater., 254-255, 141 (2013)
  15. Wu L, Li F, Xu YY, Zhang JW, Zhang DQ, Li GS, Li HX, Appl. Catal. B: Environ., 164, 217 (2015)
  16. Lee JS, Jang J, J. Ind. Eng. Chem., 20(2), 363 (2014)
  17. Nitoi I, Oancea P, Raileanu M, Crisan M, Constantin L, Cristea I, J. Ind. Eng. Chem., 20, 677 (2015)
  18. Jaeger V, Wilson W, Subramanian V, Appl. Catal. B: Environ., 110, 6 (2011)
  19. Piqueras CM, Puccia V, Vega DA, Volpe MA, Appl. Catal. B: Environ., 185, 265 (2016)
  20. Guo W, Qin Q, Geng L, Wang D, Guo YH, Yang YX, J. Hazard. Mater., 308, 372 (2016)
  21. Cheng XW, Liu HL, Yu XJ, Chen QH, Li JJ, Wang P, Umar A, Wang Q, Sci. Adv. Mater., 5, 1563 (2013)
  22. Cheng XW, Liu HL, Chen QH, Li JJ, Wang P, Electrochim. Acta, 103, 134 (2013)
  23. Ishibashi K, Fujishima A, Watanabe T, Hashimoto K, Electrochem. Commun., 2, 207 (2000)
  24. Yu JG, Dai GP, Cheng B, J. Phys. Chem. C, 114, 19378 (2010)
  25. Cheng XW, Liu HL, Chen QH, Li JJ, Wang P, Carbon, 66, 450 (2014)
  26. Han KS, Moon YS, Han OH, Hwang KJ, Kim I, Kim H, Electrochem. Commun., 9, 317 (2007)
  27. Xiong Z, Wang HB, Xu NY, Li HL, Fang BZ, Zhao YC, Zhang JY, Zheng CG, Int. J. Hydrog. Energy, 40(32), 10049 (2015)
  28. Cheng XW, Liu HL, Chen QH, Li JJ, Wang P, Electrochim. Acta, 108, 203 (2013)
  29. Cheng XW, Yu XJ, Xing ZP, Mater. Res. Bull., 47(11), 3804 (2012)
  30. Xu ZH, Yu JG, Nanoscale, 3, 3138 (2011)
  31. Li WJ, Li DZ, Zhang WJ, Hu Y, He YH, Fu XZ, J. Phys. Chem. C, 114, 2154 (2010)
  32. An TC, An JB, Yang H, Li GY, Feng HX, Nie XP, J. Hazard. Mater., 197, 229 (2011)
  33. Lin YM, Li DZ, Hu JH, Xiao GC, Wang JX, Li WJ, Fu XZ, J. Phys. Chem. C, 116, 5764 (2012)
  34. Ye LQ, Liu JY, Gong CQ, Tian LH, Peng TY, Zan L, ACS Catal., 2, 1677 (2012)
  35. Chen YM, Lu AH, Li Y, Zhang LS, Yip HY, Zhao HJ, An TC, Wong PK, Environ. Sci. Technol., 45, 5689 (2011)
  36. Song YY, Roy P, Paramasivam I, Schmuki P, Angew. Chem.-Int. Edit., 49, 351 (2010)
  37. Cleuvers M, Ecotox. Environ. Safe., 59, 309 (2004)
  38. Cheng XW, Pan GP, Yu XJ, Electrochim. Acta, 156, 94 (2015)