The Ca1-xPrxMnO3 (0 <= x <= 0.3) powders were synthesized by sol-gel auto-combustion technology and the inherent relations among chemical composition, structure, and electrical properties of the Ca1-xPrxMnO3 powders were elucidated. The results indicate that the resistivity decreases first and then increases with the increase in x and its lowest value is 0.3503 Omega.m with x = 0.25. X-ray diffraction results indicate that with the increase in x, the diffraction intensity of (220) crystal plane is strengthened and the diffraction peaks move to small angles. Through SEM images, it can be found that powders have the minimum grain size and the distribution of grain size is uniform at x = 0.25. With the increase in Pr proportion, the distortion of unit cell is intensified and the resistivity changes correspondingly. The resistivity of the Ca1-xPrxMnO3 powders is inversely proportional to the ratio of Mn3+/Mn4+, the resistivity becomes lower when the ratio of Mn3+/Mn4+ gets larger. (C) 2016 Elsevier Ltd. All rights reserved.