Some of the problems of current electrolytes for high voltage Li-ion cells originate from ethylene carbonate (EC) which is thought to be an essential electrolyte component for Li-ion cells. Ethylene carbonate-free electrolytes containing 1 M LiPF6 in ethylmethyl carbonate (EMC) with small loadings of vinylene carbonate, fluoroethylene carbonate, or (4R,5S)-4,5-Difluoro-1,3-dioxolan-2-one acting as "enablers" were developed. These electrolytes used in Li(Ni0.4Mn0.4Co0.2)O(2)(/)graphite pouch type Li-ion cells tested at 4.2 V and 4.5 V yielded excellent charge-discharge cycling and storage properties. The results for cells containing linear alkyl carbonate electrolytes with no EC were compared to those of cells with EC-containing electrolytes incorporating additives proven to enhance cyclability of cells. The combination of EMC with appropriate amounts of these enablers yields cells with better performance than cells with EC-containing electrolytes incorporating additives tested to 4.5 V. Further optimizing these linear alkyl carbonate electrolytes with appropriate co-additives may represent a viable path to the successful commercial utilization of NMC/graphite Li-ion cells operated to 4.5 V and above. (C) 2016 Elsevier B.V. All rights reserved.