Structural, Spectroscopic, and Photochemical Investigation of an Octahedral NO-Releasing {RuNO}(7) Species

Levin N; Codesido NO; Bill E; Weyhermueller T; Gaspari APS; da Silva RS; Olabe JA; Slep LD

Inorganic Chemistry, Vol.55, No.16, 7808-7810, 2016

DOI10.1021/acs.inorgchem.6b00719 Export Citation

Structural, Spectroscopic, and Photochemical Investigation of an Octahedral NO-Releasing {RuNO}(7) Species

Levin N, Codesido NO, Bill E, Weyhermueller T, Gaspari APS, da Silva RS, Olabe JA, Slep LD

[Ru(Me-3[9]aneN(3))(bpy)(NO)](BF4)(2) ([1](BF4)(2)) was explored by single-crystal X-ray diffractometry, leading to the first crystal structure of an octahedral {RuNO}(7) complex. The metal resides on the center of a distorted octahedron, with d(N-O) and