국내 유통 중인 석유제품 내 석유계 총 탄화수소화합물(TPH) 분석

임영관; 김정민; 김종렬; 권민정; 이경흠; 류승현; Young-Kwan Lim; Jeong-Min Kim; Jong-Ryeol Kim; Min-Jeong Kwon; Kyoung-Heum Lee; Seong-Hyun Ryu

Applied Chemistry for Engineering, Vol.27, No.5, 546-550, October, 2016

DOI10.14478/ace.2016.1065 Export Citation

국내 유통 중인 석유제품 내 석유계 총 탄화수소화합물(TPH) 분석

Analysis of Total Petroleum Hydrocarbon in Domestic Distribution Petroleum

임영관 ^†, 김정민, 김종렬, 권민정, 이경흠, 류승현

한국석유관리원

Young-Kwan Lim^†, Jeong-Min Kim, Jong-Ryeol Kim, Min-Jeong Kwon, Kyoung-Heum Lee, and Seong-Hyun Ryu

Korea Petroleum Quality & Distribution Authority, Chungcheongbuk-Do 28115, Korea

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초록

국내 토양오염의 60~70% 이상이 석유제품에 의한 오염이며, 석유제품에 의해 토양오염이 발생될 경우, 토양환경보전법 상 B.T.E.X와 total petroleum hydrocarbon (TPH)를 분석하도록 명시하고 있다. 본 연구에서는 국내 유통 중인 석유제품에 대한 구간별 TPH 패턴을 분석하였다. 또한 C8~C40 구간만을 분석하는 현행 토양오염공정시험기준의 문제점을 보완하여 석유제품 내 TPH를 정량분석 하였다. 분석결과, 토양오염공정시험기준 분석조건으로 분석한 결과값과 보완된 분석방법을 이용했을 시, 휘발유와 용제 1호 같은 저비점 유류의 경우, 최대 85%의 차이가 발생하는 것을 확인하였다.

Over 60~70% of the domestic soil contamination have occurred by petroleum products. B.T.E.X including benzene, toluene, ethylbenzene, xylene and total petroleum hydrocarbon (TPH) have to be inspected for the contaminated soil by petroleum products. An accurate contamination analysis is necessary to estimate the are of contaminated soil and also establish an appropriate purification scheme. In this study, we analyzed a sectional TPH pattern for current domestic distributed petroleum products. Also, the TPH content was analyzed by compensating the defect of current Korea standard analytic methods for soil where the analytic range is just for C8~C40. The light distillate petroleum products such as gasoline and solvent 1 showed the maximum of 85% difference in the TPH content between the standard analytic and improved methods.

Keywords:TPH (total petroleum hydrocarbon);soil contamination;Korean standard for soil analysis;light distillate petroleum

[References]

Portha JF, Louret S, Pons MN, Jaubert JN, Resour. Conserv. Recycl., 54, 291 (2010)
Tobiszewski M, Namiesnik J, Environ. Pollut., 162, 110 (2012)
Yun SM, Kang CS, Kim J, Kim HS, J. Hazard. Mater., 287, 429 (2015)
Lim YK, Jeong CS, Han KW, Jang YJ, Appl. Chem. Eng., 25(1), 27 (2014)
The Ministry of Environment, Korea, http://www.me.go.kr.
Kim YK, Development of Microbial Additives on Bioremediation of Oil-contaminated Soil, MS Thesis, Myongji University, Korea (2002).
Soil Environment Conservation Act, Degree of the Ministry of Environment-463, Korea.
Korean Standard for the Analysis of Contaminated Soil, Ministryof Environment, Korea.
Korea Petroleum Quality & Distribution Authority, http://www.kpetro.or.kr.
Business Act for Quality Standard, Inspection Method and Inspection Fee of Petroleum Product, Ministry of Commerce, Industry and Energy, 2015-140, Korea.
EPA Method 8015B, Nonhalogenated organics using GC/FID.

[Related Articles]

[1] Portha JF, Louret S, Pons MN, Jaubert JN, Resour. Conserv. Recycl., 54, 291 (2010)

[2] Tobiszewski M, Namiesnik J, Environ. Pollut., 162, 110 (2012)

[3] Yun SM, Kang CS, Kim J, Kim HS, J. Hazard. Mater., 287, 429 (2015)

[4] Lim YK, Jeong CS, Han KW, Jang YJ, Appl. Chem. Eng., 25(1), 27 (2014)

[5] The Ministry of Environment, Korea, http://www.me.go.kr.

[6] Kim YK, Development of Microbial Additives on Bioremediation of Oil-contaminated Soil, MS Thesis, Myongji University, Korea (2002).

[7] Soil Environment Conservation Act, Degree of the Ministry of Environment-463, Korea.

[8] Korean Standard for the Analysis of Contaminated Soil, Ministryof Environment, Korea.

[9] Korea Petroleum Quality & Distribution Authority, http://www.kpetro.or.kr.

[10] Business Act for Quality Standard, Inspection Method and Inspection Fee of Petroleum Product, Ministry of Commerce, Industry and Energy, 2015-140, Korea.

[11] EPA Method 8015B, Nonhalogenated organics using GC/FID.