화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Chemical Engineering Research, Vol.54, No.5, 636-647, October, 2016
DOI10.9713/kcer.2016.54.5.636  Export Citation
Immobilization of the Thenoyltrifluoroacetone on Sodium Dodecyl Sulfate Modified Magnetite Nanoparticles for Magnetic Solid Phase Extraction of Pb (II) from Water Samples
Meysam Sadeghi†, Sina Yekta1, and Esmaeil Babanezhad2
  • Young Researchers and Elite Club, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
  • 1Department of Chemistry, Faculty of Basic Sciences, Islamic Azad University, Qaemshahr Branch, Qaemshahr, Iran
  • 2Department of Applied Chemistry, Faculty of Pharmaceutical Chemistry, Pharmaceutical Sciences Branch, Islamic Azad University, Tehran, Iran
E-mail:
Magnetite nanoparticles (Fe3O4 NPs) were synthesized by co-precipitating method under optimized condition. The Fe3O4 NPs coated with sodium dodecyl sulfate-thenoyltrifluoroacetone (Fe3O4 NPs-SDS-TTFA) were then exerted as the magnetic solid phase extraction (MSPE) adsorbent for the extraction process prior to introducing to a flame atomic adsorption spectrometry (FAAS). The synthesized Fe3O4 NPs-SDS-TTFA were applied for the extraction of Pb(II) ions from different water samples. The characterization studies of nanoparticles were performed via scanning electron microscopy-energy dispersive micro-analysis (SEM-EDAX), X-ray diffraction (XRD) and vibrating sample magnetometer (VSM) techniques. The substantial parameters affecting the extraction efficiency were surveyed and optimized. A dynamic linear range (DLR) of 10.400 μg L-1 was obtained and the limit of detection (LOD, n=7) and relative standard deviation (RSD%, n= 6, C=20 μg L-1) were found to be 2.3 μg L-1 and 1.9%, respectively. According to the results, the proposed method successfully applied for the extraction of Pb(II) ions from different environmental water samples and satisfactory results achieved.
Keywords:Magnetite (Fe3O4) NPs;Sodium dodecyl sulfate (SDS);Thenoyltrifluoroacetone (TTFA);Extraction;Pb(II);Water sample
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