화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.41, 23-32, September, 2016
DOI10.1016/j.jiec.2016.06.023  Export Citation
Development of a novel high-flux PVDF-based ultrafiltration membrane by embedding Mg-Al nanolayered double hydroxide
Samira Arefi-Oskoui1, Vahid Vatanpour2, and Alireza Khataee1, 3, †
  • 1Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, 51666-16471 Tabriz, Iran
  • 2Faculty of Chemistry, Kharazmi University, 15719-14911 Tehran, Iran
  • 3Department of Nanotechnology, Near East University, 99138 Nicosia, North Cyprus, Mersin 10, Turkey
E-mail:
Mg-Al nanolayered double hydroxide (Mg-Al NLDH) as a hydrophilic filler was used to develop a highflux PVDF-based ultrafiltration membrane. The prepared blended membranes were characterized using SEM, EDAX, AFM and water contact angle techniques. The results indicated that the pure water flux was significantly increased from 473.8 L/m2 h for the bare (M-0) to 702.2 L/m2 h for blended membrane containing 0.5 wt% of Mg-Al NLDH (M-0.5). The performance of the bare and optimum membrane containing 0.5 wt% of NLDH was investigated for whey protein concentration, and the results indicated that the blended membrane had better antifouling property.
Keywords:Nanocomposite;Ultrafiltration;Polyvinylidene fluoride;Nanolayered double hydroxides;Whey protein concentration
  1. Mulder J, Basic principles of membrane technology, Springer Science & Business Media, 2012.
  2. Matos M, Garcıa CF, Suarez MA, Pazos C, Benito JM, J. Taiwan Inst. Chem. Eng., 59, 295 (2016)
  3. Lu H, Zou W, Chai P, Wang J, Bazinet L, J. Clean Prod., 112(Pt 4), 3097 (2016)
  4. Li NN, Fane AG, Ho WW, Matsuura T, Advanced membrane technology and applications, John Wiley & Sons, 2011.
  5. Tan XY, Tan SP, Teo WK, Li K, J. Membr. Sci., 271(1-2), 59 (2006)
  6. Bottino A, Capannelli G, Comite A, Desalination, 183(1-3), 375 (2005)
  7. Wu B, Li K, Te WK, J. Appl. Polym. Sci., 106(3), 1482 (2007)
  8. Tao MM, Liu F, Ma BR, Xue LX, Desalination, 316, 137 (2013)
  9. Wang QY, Wang ZW, Wu ZC, Desalination, 297, 79 (2012)
  10. Liu F, Hashim NA, Liu YT, Abed MRM, Li K, J. Membr. Sci., 375(1-2), 1 (2011)
  11. Safarpour M, Khataee A, Vatanpour V, Ind. Eng. Chem. Res., 53(34), 13370 (2014)
  12. Abdolmohammad-Zadeh H, Rezvani Z, Sadeghi G, Zorufi E, Anal. Chim. Acta, 685, 212 (2011)
  13. Sepehr MN, Yetilmezsoy K, Marofi S, Zarrabi M, Ghaffari HR, Fingas M, Foroughi M, J. Taiwan Inst. Chem. Eng., 45, 2786 (2014)
  14. Yin HS, Cui L, Ai SY, Fan H, Zhu LS, Electrochim. Acta, 55(3), 603 (2010)
  15. Mandal S, Mayadevi S, Appl. Clay Sci., 40, 54 (2008)
  16. Xu ZP, Stevenson G, Lu CQ, Lu GQ, J. Phys. Chem. B, 110(34), 16923 (2006)
  17. Liu JD, Yu L, Zhang YT, Desalination, 335(1), 78 (2014)
  18. Lu P, Liang S, Qiu L, Gao Y, Wang Q, J. Membr. Sci. (2016)
  19. Bradford MM, Anal. Biochem., 72, 248 (1976)
  20. Rahimpour A, Madaeni SS, Mansourpanah Y, J. Membr. Sci., 364(1-2), 380 (2010)
  21. Chang IS, Kim SN, Process Biochem., 40(3-4), 1307 (2005)
  22. Zhao S, Wang Z, Wei X, Zhao BR, Wang JX, Yang SB, Wang SC, J. Membr. Sci., 385(1-2), 251 (2011)
  23. van der Marel P, Zwijnenburg A, Kemperman A, Wessling M, Temmink H, van der Meer W, J. Membr. Sci., 348(1-2), 66 (2010)
  24. Patterson A, Phys. Rev., 56, 978 (1939)
  25. Kim DY, Joo EH, Mishra AK, Kim NH, Na YJ, Lee JH, Synthesis and Characterization of SPEEK/Layered Double Hydroxide Polymer Nanocomposite for Fuel Cell Applications, Trans. Tech. Publ., 2013, p. 234.
  26. Abdolmohammad-Zadeh H, Nejati K, Ghorbani E, Chem. Eng. Commun., 202(10), 1349 (2015)
  27. Jahangiri H, Lehi AY, Akbari A, Desalination, 375, 116 (2015)
  28. Lee KW, Seo BK, Nam ST, Han MJ, Desalination, 159(3), 289 (2003)
  29. Mehrnia MR, Mojtahedi YM, Homayoonfal M, Desalination, 372, 75 (2015)
  30. Yu LY, Xu ZL, Shen HM, Yang H, J. Membr. Sci., 337(1-2), 257 (2009)
  31. Bae TH, Tak TM, J. Membr. Sci., 249(1-2), 1 (2005)
  32. Yan L, Li YS, Xiang CB, Xianda S, J. Membr. Sci., 276(1-2), 162 (2006)
  33. Oh SJ, Kim N, Lee YT, J. Membr. Sci., 345(1-2), 13 (2009)
  34. Baldasso C, Barros TC, Tessaro IC, Desalination, 278(1-3), 381 (2011)
  35. Arunkumar A, Etzel MR, J. Membr. Sci., 475, 340 (2015)
  36. Rana D, Matsuura T, Chem. Rev., 110(4), 2448 (2010)
  37. Cheng Y, Wei H, Sun R, Tian Z, Zheng X, Anal. Biochem., 494, 37 (2016)