Adsorption and desorption property of iminodiacetate resin (Lewatit® TP207) for indium recovery

Su-Kyung Lee; U-Hwang Lee

Journal of Industrial and Engineering Chemistry, Vol.40, 23-25, August, 2016

DOI10.1016/j.jiec.2016.05.016 Export Citation

Adsorption and desorption property of iminodiacetate resin (Lewatit® TP207) for indium recovery

Su-Kyung Lee¹, and U-Hwang Lee^{1, 2, †}

¹Center for Nanocatalysts, Korea Research Institute of Chemical Technology (KRICT), 141 Gajeong-Ro, Yuseong, Daejeon 305-600, Republic of Korea
²Department of Green Chemistry, University of Science and Technology (UST), 217 Gajeong-Ro, Yuseong, Daejeon 305-350, Republic of Korea

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The adsorption and desorption characteristics for indium recovery from aqueous solutions using commercially available iminodiacetate resin Lewatit®TP207 (TP207) was investigated. The polymer resin had indium adsorption capacity of 55 mgIn/gTP207 at 25℃ and desorption efficiency of 99% in pH 0.8 acid aqueous solution. Furthermore, it was observed that TP207 had performance result of 99% after four times cycle test to confirm the reusability. The results show that TP207 polymer resin provides high efficient desorption property in acid solution and reusability in cycle test of adsorption.desorption. These results offer a simple and effective recovery process for indium.

Keywords:Indium Recovery;Iminodiacetate;Lewatit® TP207

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[1] Annual Report 2012, Securities and Exchange Commission, US, http://www.sec.gov/Archives/edgar/data/1426506/000114420413019117/v336853_10k.htm.

[2] Materials Information System, European Commission, https://setis.ec.europa.eu/mis/material/indium.

[3] Li J, Gao S, Duan H, Liu L, Waste Manage., 29, 2033 (2009)

[4] Tuzen M, Soylak M, J. Hazard. Mater., 129(1-3), 179 (2006)

[5] Zhan L, Xia FF, Ye QY, Xiang XS, Xie B, J. Hazard. Mater., 299, 388 (2015)

[6] Fontana D, Forte F, Carolis RD, Grosso M, Waste Manage., 45, 325 (2015)

[7] Silveira AVM, Fuchs MS, Pinheiro DK, Tanabe EH, Bertuol DA, Waste Manage., 45, 325 (2015)

[8] Wang H, Gu Y, Wu Y, Zhang YN, Wang W, Waste Manage., 46, 480 (2015)

[9] Rocchetti L, Amato A, Fonti V, Ubaldini S, Michelis ID, Kopacek B, Veglio F, Beolchini F, Waste Manage., 42, 180 (2015)

[10] Minamisawa H, Murashima K, Minamisawa M, Arai N, Okutani T, Anal. Sci., 19, 401 (2003)

[11] Gupta B, Deep A, Malik P, Anal. Chim. Acta, 513, 463 (2004)

[12] Swain B, Mishra C, Hong HS, Cho SS, Lee SK, Green Chem., 17, 3979 (2015)

[13] Swain B, Mishra C, Hong HS, Cho SS, Green Chem., 17, 4418 (2015)

[14] Ferreira EDM, Morelli T, Moreira IMNS, de Carvalho MS, J. Braz. Chem. Soc., 15, 563 (2004)

[15] Bermejo-Barrera P, Martinez-Alsonso N, Bermejo-Barrera A, Fresenius J. Anal. Chem, 369, 191 (2001)

[16] Dubey RK, Puri S, Gupta MK, Puri BK, Anal. Lett., 31, 2729 (1998)

[17] Taher MA, Talanta, 52, 301 (2000)

[18] Masi AN, Olsina RA, J. Trace Microprobe Tech., 17, 315 (1999)

[19] Wei JS, Liu Q, Okutani T, Anal. Sci., 10, 465 (1994)

[20] Tong A, Akama Y, Tanaka S, Anal. Chim. Acta, 230, 175 (1990)

[21] Ershova NI, Ivanov VM, Anal. Chim. Acta, 364, 235 (1998)

[22] Hasegawa H, Rahman IMM, Umehara Y, Sawai H, Maki T, Furusho Y, Mizutani S, Microchem J., 110, 133 (2013)

[23] Inoue K, J. Mining Mater. Proc. Inst. Jpn., 105, 751 (1989)

[24] Roqai MC, Goetz-Grandmont GJ, Brunette JP, Analusis, 26, 74 (1998)

[25] Hasegawa Y, Shimada T, Niitsu M, J. Inorg. Nucl. Chem., 42, 1487 (1980)

[26] Sato T, Yasumura H, Mizuno Y, Nishimura T, Proc. Int. Sol. Extr. Conf. Melbourne(Austral), 559 (1996)

[27] Rodriguez MA, Cote G, Bauer D, Solvent Extr. Ion Exch., 10, 811 (1992)

[28] Fortes MCB, Martins AH, Benedetto JS, Miner. Eng., 16(7), 659 (2003)

[29] Fortes MCB, Martins AH, Benedetto JS, Braz. J. Chem. Eng., 24, 287 (2007)

[30] Xiong C, Yao C, Rare Metals, 27, 153 (2008)

[31] Physical and Chemical Property of TP207, http://www.lenntech.com/Data-sheets/Lewatit-TP-207-L.pdf.