화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.120, No.25, 4343-4348, 2016
Transition-Selective Pulses in Zero-Field Nuclear Magnetic Resonance
We use low-amplitude, ultralow frequency pulses to drive nuclear spin transitions in zero and ultralow magnetic fields. In analogy to high-field NMR, a range of sophisticated experiments becomes available as these allow narrow-band excitation. As a first demonstration, pulses with excitation bandwidths 0.5-5 Hz are used for population redistribution, selective excitation, and coherence filtration. These methods are helpful when interpreting zero- and ultralow-field NMR spectra that contain a large number of transitions.