The results of an experimental study of the effect of gas agitation on mass transfer from cylindrical Si specimens to molten Al were used to deduce mean mass transfer coefficients in a two-phase flow. Then the three-dimensional gas-agitated liquid was simulated using the commercial software FLOW-3D, to obtain predictions of bubble distribution and estimates of the velocity field within the opaque liquid metal, to be used to predict mass transfer rates. An existing mass transfer correlation for a gas-agitated liquid without an external bulk flow was used to fit the experimental data within 5%. With a bulk velocity, a correlation for mass transfer from a vertical cylinder in cross flow was modified to incorporate the effect of gas injection, and it predicted the measured mass transfer coefficients within 11%. (C) 2016 Elsevier Ltd. All rights reserved.