Crude glycerol-mediated liquefaction of saccharification residues of sunflower stalks for production of lignin biopolyols

Keon Hee Kim; Ju-Hyun Yu; Eun Yeol Lee

Journal of Industrial and Engineering Chemistry, Vol.38, 175-180, June, 2016

DOI10.1016/j.jiec.2016.05.002 Export Citation

Crude glycerol-mediated liquefaction of saccharification residues of sunflower stalks for production of lignin biopolyols

Keon Hee Kim, Ju-Hyun Yu^{1, †}, and Eun Yeol Lee^†

Department of Chemical Engineering,, Kyung Hee University, Gyeonggi-do 446-701, Republic of Korea
¹Center for Bio-based Chemistry, Convergence Biochemistry Division, Korea Research Institute of Chemical Technology, P.O. Box 107, 141 Gajeong-ro, Yuseong-gu, Daejeon 305-600, Republic of Korea

E-mail:,

Biopolyol was produced by the liquefaction of the sunflower stalk saccharification residues using a biodiesel-derived crude glycerol as a liquefaction solvent. Biopolyol was produced under the optimal conditions of 10% (w/w) biomass loading, 4% (w/w) sulfuric acid loading at 150 ℃ and for 60 min. Biomass conversion was 59%, and the hydroxyl and acid number numbers were 1460 and 11 mg KOH/g biopolyol, respectively. The bio-PU was synthesized from the biopolyol and methylene diphenyl diisocyanate (MDI). Fourier transform infrared spectroscopy (FTIR) showed that bio-PU was successfully synthesized from biopolyols and MDI.

Keywords:Sunflower stalk;Saccharification residue;Liquefaction;Biopolyol;Biopolyurethane

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[Referenced By]

[1] Eom IY, Yu JH, J. Ind. Eng. Chem., 23, 72 (2015)

[2] Zhang H, Ding F, Luo C, Xiong L, Chen X, Ind. Crop. Prod., 39, 47 (2012)

[3] Matsushita Y, Yasuda S, Bioresour. Technol., 96(4), 465 (2005)

[4] Jung CD, Yu JH, Eom IY, Hong KS, Bioresour. Technol., 138, 1 (2013)

[5] Vaithanomsat P, Chuichulcherm S, Apiwatanapiwat W, World Acad. Sci. Eng. Technol., 25, 140 (2009)

[6] Caparros S, Ariza J, Lopez F, Nacimiento JA, Garrote G, Jimenez L, Bioresour. Technol., 99(5), 1368 (2008)

[7] Brebu M, Vasile C, Cellul. Chem. Technol., 44, 353 (2010)

[8] Wang H, Chen HZ, J. Chin. Inst. Chem. Eng., 38(2), 95 (2007)

[9] Yao YG, Yoshioka M, Shiraishi N, J. Appl. Polym. Sci., 60(11), 1939 (1996)

[10] El-barbary MH, Shukry N, Ind. Crop. Prod., 27, 33 (2008)

[11] Yan YB, Pang H, Yang XX, Zhang RL, Liao B, J. Appl. Polym. Sci., 110(2), 1099 (2008)

[12] Chen FG, Lu ZM, J. Appl. Polym. Sci., 111(1), 508 (2009)

[13] Jin YQ, Ruan XM, Cheng XS, Lu QF, Bioresour. Technol., 102(3), 3581 (2011)

[14] Li Y, Han Y, Qin TF, Chu J, Biobased Mater. Bioenergy, 6, 51 (2012)

[15] Lee SH, Teramoto Y, Shiraishi N, J. Appl. Polym. Sci., 83(7), 1482 (2002)

[16] Yu F, Le ZP, Chen P, Liu YH, Lin XY, Ruan R, Appl. Biochem. Biotechnol., 148(1-3), 235 (2008)

[17] Lee SH, Yoshioka M, Shiraishi N, J. Appl. Polym. Sci., 78(2), 319 (2000)

[18] Hu SJ, Wan CX, Li YB, Bioresour. Technol., 103(1), 227 (2012)

[19] Thompson JC, He BB, Appl. Eng. Agric., 22, 261 (2006)

[20] Nanda MR, Yuan Z, Qin W, Poirier MA, Chunbao X, Austin J. Chem. Eng., 1, 1 (2014)

[21] Johnson DT, Taconi KA, Environ. Prog., 26, 338 (2007)

[22] Li C, Luo X, Li T, Tong X, Li Y, Polymer, 55, 6529 (2014)

[23] Jo YJ, Ly HV, Kim J, Kim SS, Lee EY, J. Ind. Eng. Chem., 29, 304 (2015)

[24] Briones R, Serrano L, Llano-Ponte R, Labidi J, Chem. Eng. J., 175, 169 (2011)

[25] Ye LY, Zhang JM, Zhao J, Tu S, Bioresour. Technol., 153, 147 (2014)

[26] Li Y, Han Y, Qin T, Chu F, J. Biobased Mater. Bioenergy, 6, 51 (2012)

[27] Yamada T, Ono H, J. Wood Sci., 47, 458 (2001)

[28] Lee JH, Lee JH, Kim DK, Park CH, Yu JH, Lee EY, J. Ind. Eng. Chem., 34, 157 (2016)

[29] Luo XL, Hu SJ, Zhang X, Li YB, Bioresour. Technol., 139, 323 (2013)

[30] Shen L, Haufe J, Patel MK, Product Overview and Market Projection of Emerging Bio-based Plastics, PROBIP, 2009.

[31] Kapps M, Buschkamp S, The production of rigid polyurethane foam. Bayer Materials Science AG, Leverkusen, Germany, 2004.

[32] Ionescu M, Petrovic ZS, J. Cell. Plast., 46, 223 (2010)

[33] Xu J, Jiang J, Hse CY, Shupe TF, J. Appl. Polym. Sci., 131 (2014)

[34] Bernardini J, Cinelli P, Anguillesi I, Coltelli MB, Lazzeri A, Eur. Polym. J., 64, 147 (2015)

[35] Wong CS, Badri KH, Mater. Sci. Appl., 3, 78 (2012)

[36] Liang L, Mao Z, Li Y, Wan C, Wang T, Zhang L, Zhang L, BioResources, 1, 248 (2007)