Mn-doped TiO2 grown on reduced graphene oxide(rGO) was synthesized by one -pot hydrothermal method and the photocatalytic removal of Cr by the material was investigated under sunlight. The materials were characterized by a combination of scanning electron microscopy, transmission electron microscopy, X-ray diffraction, thermogravimetric analysis, Brunauer-Emmett-Teller method, UV-vis diffuse reflectance spectra, photoluminescence spectra, electrochemical impedance spectroscopy and X-ray photoelectron spectroscopy. Cr(total) removal efficiency of the material is 97.32% in 30 min and 99.02% in 60 min under sunlight irradiation, as the initial concentration of Cr(VI) is 20 mg/L. The high photocatalytic activity under visible light is considered mainly due to the Mn-doping, and rGO plays an important role in the synergetic effect of adsorption and photocatalysis to sustain the high efficient removal of Cr(VI) and Cr(III). Cr(VI) adsorbed on the surface of rGO is reduced to Cr(III) by photo electrons which are transported through rGO, and the reaction. product Cr(III) continues to be adsorbed. The process contributes to the release of abundant photocatalytic sites of Mn-TiO2 and improves photocatalytic efficiency. The excellent adsorption and photocatalytic effect with the explanation of the synergetic mechanism are very useful not only for fundamental research but also for the potential practical applications. (C) 2016 Elsevier B.V. All rights reserved.