In situ grown pyramid structures of nickel diselenides (NiSe2) have been synthesized using oxidized nickel foam(NF(Ox)) assubstrate bya facile solvothermal selenization. XRDresults show that NiSe phaseonNFand NiSe2 phase on NF (Ox) have been obtained after the identical selenization process, respectively. The nanorods morphology of NiSe on NF and pyramid structure of NiSe2 on NF (Ox) have been revealed by SEM images. The different structure and morphology of NiSe/NF compared with NiSe2/NF (Ox) can be ascribed to the oxidation pretreatment of NF which affiliates the formation of ultrathin beta-Ni(OH)(2) nanosheets on NF. The electrochemical measurements for oxygen evolution reaction (OER) exhibit an enhanced electrocatalytic activity of NiSe2/NF (Ox) with onset potential of 1.54 V (vs. RHE) and small Tafel slope of 96 mV dec(-1). Moreover, NiSe2/NF (Ox) possesses lower charge-transfer resistance (R-ct) indicating a faster electron transfer rate than NiSe/NF. The excellent stability further confirms the improved elctrocatalytic performance of NiSe2/NF (Ox). We speculate that the high Ni2+ proportion and octahedral structure of NiSe2 may be the keys for excellent electrocatalytic properties for OER. (C) 2016 Elsevier Ltd. All rights reserved.