Ag3PO4 photocatalysts were prepared via two and one-step through a facile ion-exchange route. The photocatalysts were then characterized through powder X-ray diffraction, scanning electron microscopy and UV-vis diffuse reflectance spectroscopy. The photocatalytic activity of the samples was evaluated on the basis of the photocatalytic degradation of methyl orange (MO) and methylene blue (MB) under solar irradiation. The MO degradation rate of the Photocatalyst synthesized by the two-step ion-exchange route was 89.18% in 60 min. This value was four times that of the Photocatalyst synthesized by the one-step approach. The MB degradation rate was 97% in 40 min. After six cycling runs were completed, the MO degradation rate was 73% (C) 2016 Elsevier B.V. All rights reserved.