화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.37, 306-311, May, 2016
DOI10.1016/j.jiec.2016.03.037  Export Citation
Combination of dispersive liquid.liquid microextraction and multivariate optimization for separation-enrichment of traces lead by flame atomic absorption spectrometry
M.A. Habila, E. Yilmaz1, Z.A. ALOthman, and M. Soylak1, †
  • Chemistry Department, College of Science, King Saud University, Riyadh-11451, Kingdom of Saudi Arabia
  • 1Faculty of Sciences, Department of Chemistry, Erciyes University, 38039-Kayseri-Turkey
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This work presents a method for the preconcentration of lead using dispersive liquid-liquid microextraction. 2,2' Dithiobis (benzothiazole) was used as the chelating agent, and chloroform was selected as the extraction solvent. Parameters such as: pH, volume of ligand, volume of extraction solvent and dispersive solvent volume affecting on the extraction efficiency of method has been evaluated by Plackett.Burman design. The limit of detection and limit of quantification were 4.3 μg L-1 and 14.2 μg L-1, respectively. The accuracy of the method was evaluated by analyzing certified reference materials. Method was applied to the determination of lead in water samples.
Keywords:Dispersive liquid liquid microextraction;Lead;Multivariate optimization;Plackett-Burman design;Central composite design
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