Journal of Chemical Thermodynamics, Vol.88, 30-35, 2015
Solubilities of isobutane and cyclopropane in ionic liquids
In this work, we presented the solubilities of isobutane and cyclopropane in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ([HMIM][Tf2N]) and trihexyl tetradecylphosphonium bis(2,4,4-trimethylpentyl) phosphinate ([P(14)666][TMPP]) from T = (302 to 344) K up to 1.16 MPa. Henry's constants for isobutane and cyclopropane in [HMIM][Tf2N] and [P(14)666][TMPP] were calculated from experimental results. Solubilities of isobutane and cyclopropane in [HMIM][Tf2N] are apparently smaller than those in [P(14)666][TMPP]. The effects of temperature, pressure and the number of carbon atoms in the hydrocarbons on the solubility were investigated in detail. A modified Krichevsky-Kasarnovsky equation was successfully applied to correlate the experimental results. The mean absolute relative deviations and the maximum absolute relative deviations are less than (2.4 and 4.6)%, respectively. (C) 2015 Elsevier Ltd. All rights reserved.