Journal of Crystal Growth, Vol.442, 25-30, 2016
MOCVD growth of N-polar GaN on on-axis sapphire substrate: Impact of AIN nucleation layer on GaN surface hillock density
We report on the impact of growth conditions on surface hillock density of N-polar GaN grown on nominally on-axis (0001) sapphire substrate by metal organic chemical vapor deposition (MOCVD). Large reduction in hillock density was achieved by implementation of an optimized high temperature AIN nucleation layer and use of indium surfactant in GaN overgrowth. A reduction by more than a factor of five in hillock density from 1000 to 170 hillocks/cm(-2) was achieved as a result. Crystal quality and surface morphology of the resultant GaN films were characterized by high resolution x-ray diffraction and atomic force microscopy and found to be relatively unaffected by the buffer conditions. It is also shown that the density of smaller surface features is unaffected by AIN buffer conditions. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Atomic force microscopy;Hexagonal hillock;Polarity;Metalorganic chemical vapor deposition;Nitrides