High surface area and light scattering abilities are dispensable for a well-performed photoanode of dye-sensitized solar cells (DSSCs) to respectively provide abundant active sites for dye adsorption and enhance the light path for electron excitation. In this study, an energy-saving and cost-effective low-temperature (80 degrees C) aqueous solution method is applied to synthesize dual-functional ZnO aggregates which are composed of small nanocrystallites with the diameter of 20 nm. The reaction time plays a significant role in controlling the morphology of ZnO nanostructures. The ZnO aggregates are randomly oriented at the early stage and the flower-like morphology gradually forms when the reaction time reaches 4 h, while the well-defined structure is further destroyed when the reaction time is increased to 8 h. The growth mechanism is proposed to discuss the formation of ZnO nanoflower. The ZnO nanoflower-based DSSC achieves a light-to-electricity conversion efficiency (eta) of 4.41%, which is higher than that for the cell with commercial ZnO nanoparticles on its photoanode (3.42%) under AM 1.5G simulated sunlight with an intensity of 100 mW/cm(2). The electrochemical impedance spectroscopy (EIS) is also applied to analyze the electron transport parameters to understand the kinetics of electron transport in the ZnO films. The low-temperature (150 degrees C) fabrication process for preparing the highly-performed ZnO film also enables the future applications of flexible DSSCs with polymeric substrates. (C) 2015 Elsevier B.V. All rights reserved.