Electrochemical potential noise analysis was used to investigate corrosion behavior of copper electrodes in presence of 0.001, 0.005, 0.01 and 0.02 M benzotriazole (BTA) inhibitor. Energy distribution of the potential noise was obtained from wavelet transformation using the 4th order Daubechies pattern. Two lowest frequencies were added-up and fitted to the impulse response of the first order circuit to achieve the time-constant vs. concentration (T-C) diagram. T-C diagram can be used either as a conventional diagram of inhibition efficiency or a tool for evaluation of the surface film dielectric constant. The assumptions made in this treatment were confirmed by EIS method. (C) 2009 Elsevier B.V. All rights reserved.