Organosilicate based superhydrophilic nanofilm with enhanced durability for dentistry application

Xiangde Lin; Sunghee Hwangbo; Hyejoong Jeong; Young-Ah Cho; Hyo-won Ahn; Jinkee Hong

Journal of Industrial and Engineering Chemistry, Vol.36, 30-34, April, 2016

DOI10.1016/j.jiec.2016.02.017 Export Citation

Organosilicate based superhydrophilic nanofilm with enhanced durability for dentistry application

Xiangde Lin, Sunghee Hwangbo, Hyejoong Jeong, Young-Ah Cho¹, Hyo-won Ahn², and Jinkee Hong^†

School of Chemical Engineering and Material Science, Chung-Ang University, Chung-Ang University, Korea
¹Department of Oral and Maxillofacial Pathology, School of Dentistry, Kyung Hee University, 26 Kyungheedae-ro, Dongdaemun-gu, Seoul 02447, Republic of Korea
²Department of Orthodontics, School of Dentistry, Kyung Hee University, 26 Kyungheedae-ro, Dongdaemun-gu, Seoul 02447, Republic of Korea

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The present work presents a layer-by-layer assembled nano-film with enhanced stability onto mouthguards for the first time. To obtain high thermal and mechanical durability of modified mouthguards, the silicon-based material, silsesquioxane and silica nanoparticle matrix (SiSQ), was introduced into nanofilms. Moreover, with the help of hydrogen-bonding interactions between SiSQ and a bio-compatible building block of branched polyethyleneimine (BPEI), (BPEI/SiSQ)n nanofilms were successfully prepared. Anti-bacterial property of treated mouthguards is expected to be shown in terms of film superhydrophilicity. Above all, this organosilicate-based superhydrophilic nano-film with biocompatibility and enhanced durability is of great significance, which can be applied to other biomedical platforms.

Keywords:Mouthguards;Organosilicate;Superhydrophilic coating;Cytotoxicity;Mechanical stability

[References]

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Sheridan JJ, Armbruster P, J. Clin. Orthod., 33, 339 (1999)
Lindauer SJ, Shoff RC, J. Clin. Orthod., 32, 95 (1998)
Ponitz RJ, Am. J. Orthod., 59, 266 (1971)
Schuster S, Eliades G, Zinelis S, Eliades T, Bradley TG, Am. J. Orthod. Dentofacial, 126, 725 (2004)
McNamara JA, Brudon WL, Orthodontic and Orthopedic Treatment in the Mixed Dentition, Needham Press, Ann Arbor, 1993.
Thickett E, Power S, Eur. J. Orthod., 32, 1 (2010)
Takeda T, Ishigami K, Mishima O, Karasawa K, Kurokawa K, Kajima T, Nakajima K, Dent. Traumatol., 27, 489 (2011)
Miyahara T, Dahlin C, Galli S, Parsafar S, Koizumi H, Kasugai S, Dent. Traumatol., 29, 303 (2013)
Westerman B, Stringfellow PM, Eccleston JA, Dent. Traumatol., 18, 24 (2002)
Kataoka SH, Setzer FC, Gondim E, Caldeira CL, J. Am. Dent. Assoc., 145, 956 (2014)
Zhang N, Bai Y, Ding X, Zhang Y, Dent. Mater. J., 30, 954 (2011)
Dupaix RB, Boyce MC, Polymer, 46(13), 4827 (2005)
Lu QW, Macosko CW, Polymer, 45(6), 1981 (2004)
Ma H, Yang Y, Polym. Test, 27, 441 (2008)
Torres RA, Arellano-Ceja J, Hernandez-Hernandez ME, Gonzalez-Nunez R, Polym. Bull., 59(2), 251 (2007)
Liu H, Webster TJ, Biomaterials, 28, 354 (2007)
Catledge SA, Fries MD, Vohra YK, Lacefield WR, Lemons JE, Woodard S, Venugopalanc R, J. Nanosci. Nanotechnol., 2, 293 (2002)
Wu G, Su Z, Chem. Mater., 18, 3726 (2006)
Subianto S, Mistry MK, Choudhury NR, Dutta NK, Knott R, ACS Appl. Mater. Interfaces, 1, 1173 (2009)
Wang F, Lu X, He C, J. Mater. Chem., 21, 2775 (2011)
Kim SH, Ahn SH, Hirai T, Polymer, 44(19), 5625 (2003)
Yuen SM, Ma CCM, J. Appl. Polym. Sci., 109(3), 2000 (2008)
Wang YX, Robertson JL, Spillman WB, Claus RO, Pharm. Res., 21, 1362 (2004)
Decher G, Science, 277(5330), 1232 (1997)
Caruso F, Caruso RA, Mohwald H, Science, 282(5391), 1111 (1998)
Cho J, Char K, Hong JD, Lee KB, Adv. Mater., 13(14), 1076 (2001)
Wang HL, Miyauchi M, Takata T, J. Periodont. Res., 37, 340 (2002)
Privett BJ, Youn J, Hong SA, Lee J, Han J, Shin JH, Schoenfisch MH, Langmuir, 27(15), 9597 (2011)
Tijing LD, Ruelo MTG, Amarjargal A, Pant HR, Park CH, Kim DW, Kim CS, Chem. Eng. J., 197, 41 (2012)
Cebeci FC, Wu ZZ, Zhai L, Cohen RE, Rubner MF, Langmuir, 22(6), 2856 (2006)
McCusker C, Carroll JB, Rotello VM, Chem. Commun., 8, 996 (2005)
Torricelli P, Verne E, Brovarone CV, Appendino P, Rustichelli F, Krajewski A, Ravaglioli A, Pierini G, Fini M, Giavaresi G, Biomaterials, 22, 2535 (2001)
Wong SY, Han L, Timachova K, Veselinovic J, Hyder MN, Ortiz C, Klibanov AM, Hammond PT, Biomacromolecules, 13(3), 719 (2012)
Fischer D, Li Y, Ahlemeyer B, Krieglstein J, Kissel T, Biomaterials, 24, 1121 (2003)
Kim K, Han J, Lee TR, Shin DW, Chang H, Cho AR, Choi SJ, Jo SJ, Kwon O, Ann. Dermatol., 26, 308 (2014)
Allan SM, Tyrrell PJ, Rothwell NJ, Nat. Rev. Immunol., 5, 629 (2005)
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[Referenced By]

[1] Sheridan J, LeDoux W, McMinn R, J. Clin. Orthod., 27, 37 (1993)

[2] Sheridan JJ, Armbruster P, J. Clin. Orthod., 33, 339 (1999)

[3] Lindauer SJ, Shoff RC, J. Clin. Orthod., 32, 95 (1998)

[4] Ponitz RJ, Am. J. Orthod., 59, 266 (1971)

[5] Schuster S, Eliades G, Zinelis S, Eliades T, Bradley TG, Am. J. Orthod. Dentofacial, 126, 725 (2004)

[6] McNamara JA, Brudon WL, Orthodontic and Orthopedic Treatment in the Mixed Dentition, Needham Press, Ann Arbor, 1993.

[7] Thickett E, Power S, Eur. J. Orthod., 32, 1 (2010)

[8] Takeda T, Ishigami K, Mishima O, Karasawa K, Kurokawa K, Kajima T, Nakajima K, Dent. Traumatol., 27, 489 (2011)

[9] Miyahara T, Dahlin C, Galli S, Parsafar S, Koizumi H, Kasugai S, Dent. Traumatol., 29, 303 (2013)

[10] Westerman B, Stringfellow PM, Eccleston JA, Dent. Traumatol., 18, 24 (2002)

[11] Kataoka SH, Setzer FC, Gondim E, Caldeira CL, J. Am. Dent. Assoc., 145, 956 (2014)

[12] Zhang N, Bai Y, Ding X, Zhang Y, Dent. Mater. J., 30, 954 (2011)

[13] Dupaix RB, Boyce MC, Polymer, 46(13), 4827 (2005)

[14] Lu QW, Macosko CW, Polymer, 45(6), 1981 (2004)

[15] Ma H, Yang Y, Polym. Test, 27, 441 (2008)

[16] Torres RA, Arellano-Ceja J, Hernandez-Hernandez ME, Gonzalez-Nunez R, Polym. Bull., 59(2), 251 (2007)

[17] Liu H, Webster TJ, Biomaterials, 28, 354 (2007)

[18] Catledge SA, Fries MD, Vohra YK, Lacefield WR, Lemons JE, Woodard S, Venugopalanc R, J. Nanosci. Nanotechnol., 2, 293 (2002)

[19] Wu G, Su Z, Chem. Mater., 18, 3726 (2006)

[20] Subianto S, Mistry MK, Choudhury NR, Dutta NK, Knott R, ACS Appl. Mater. Interfaces, 1, 1173 (2009)

[21] Wang F, Lu X, He C, J. Mater. Chem., 21, 2775 (2011)

[22] Kim SH, Ahn SH, Hirai T, Polymer, 44(19), 5625 (2003)

[23] Yuen SM, Ma CCM, J. Appl. Polym. Sci., 109(3), 2000 (2008)

[24] Wang YX, Robertson JL, Spillman WB, Claus RO, Pharm. Res., 21, 1362 (2004)

[25] Decher G, Science, 277(5330), 1232 (1997)

[26] Caruso F, Caruso RA, Mohwald H, Science, 282(5391), 1111 (1998)

[27] Cho J, Char K, Hong JD, Lee KB, Adv. Mater., 13(14), 1076 (2001)

[28] Wang HL, Miyauchi M, Takata T, J. Periodont. Res., 37, 340 (2002)

[29] Privett BJ, Youn J, Hong SA, Lee J, Han J, Shin JH, Schoenfisch MH, Langmuir, 27(15), 9597 (2011)

[30] Tijing LD, Ruelo MTG, Amarjargal A, Pant HR, Park CH, Kim DW, Kim CS, Chem. Eng. J., 197, 41 (2012)

[31] Cebeci FC, Wu ZZ, Zhai L, Cohen RE, Rubner MF, Langmuir, 22(6), 2856 (2006)

[32] McCusker C, Carroll JB, Rotello VM, Chem. Commun., 8, 996 (2005)

[33] Torricelli P, Verne E, Brovarone CV, Appendino P, Rustichelli F, Krajewski A, Ravaglioli A, Pierini G, Fini M, Giavaresi G, Biomaterials, 22, 2535 (2001)

[34] Wong SY, Han L, Timachova K, Veselinovic J, Hyder MN, Ortiz C, Klibanov AM, Hammond PT, Biomacromolecules, 13(3), 719 (2012)

[35] Fischer D, Li Y, Ahlemeyer B, Krieglstein J, Kissel T, Biomaterials, 24, 1121 (2003)

[36] Kim K, Han J, Lee TR, Shin DW, Chang H, Cho AR, Choi SJ, Jo SJ, Kwon O, Ann. Dermatol., 26, 308 (2014)

[37] Allan SM, Tyrrell PJ, Rothwell NJ, Nat. Rev. Immunol., 5, 629 (2005)

[38] Chambers KT, Unverferth JA, Weber SM, Wek RC, Urano F, Corbett JA, Diabetes, 57, 124 (2008)