화학공학소재연구정보센터
Thin Solid Films, Vol.603, 328-333, 2016
Deposition and characterization of ZnO films using microplasma at atmospheric pressure
Zinc oxide (ZnO) films were deposited on room-temperature Si(100) by microwave-induced microplasma at one atmosphere. The precursor used in this work was zinc acetylacetonate hydrate (Zn(acac)(2)center dot xH(2)O) sublimed at 54 degrees C into flowing helium. The deposition rate was estimated to be 400 nm/min. The films were visually transparent and FTIR spectroscopy confirms the presence of the Zn-O stretching vibration at 410 cm(-1). Raman spectroscopy reveals that the films have the 437 cm-1 Raman band typical of a wurtzite crystal structure. Cross sectional scanning electron microscopy shows columnar growth with individual column widths of approximately 0.5 mu m. Scale-up using arrays of microplasmas is considered. (C) 2016 Elsevier B.V. All rights reserved.