화학공학소재연구정보센터
Materials Chemistry and Physics, Vol.173, 161-167, 2016
Synthesis and characterization of thiolated pectin stabilized gold coated magnetic nanoparticles
Core-shell nanoparticles, magnetic core and gold shell, were synthesized by reduction of gold chloride on the surface of magnetic nanoparticles; using tyrosine as a reducing agent. The formation of gold shell on magnetic nanoparticles was confirmed by X-ray diffraction (XRD) and UV-Visible spectroscopy. The core-shell nanoparticles (CSn) were conjugated with thiolated pectin to form a stable aqueous dispersion. The hydrodynamic size of thiolated pectin stabilized core-shell nanoparticles (TP-CSn) measured by Dynamic light scattering (DLS) was 160.5 nm with a poly dispersity index (PDI) of 0.302, whereas the mean particle size of TP-CSn calculated by high resolution transmission electron microscopy (HRTEM) was 10.8 +/- 2.7 nm. The value of zeta potential for TP-CSn was -13.6 mV. There was a decrease in the value of saturation magnetization upon formation of the gold shell on magnetic nanoparticles. The amount of thiolated pectin bound to the surface of core-shell nanoparticles, calculated using Thermogravimetric analysis (TGA), was 6% of sample weight. (C) 2016 Elsevier B.V. All rights reserved.