The copper-cerium composite oxides supported on silicon carbide (SiC) catalysts (CuO-CeO2/SiC) for sulfuric acid decomposition were studied in sulfur-iodine (SI or IS) cycle. The influence of calcination temperatures (800 degrees C-1000 degrees C) of CuO-CeO2/SiC catalysts on their activities and morphology were investigated in this study. The activity of CuO-CeO2/SiC was prominently higher than that of CuO-CeO2 composite oxides catalyst. The SO3 conversion ratio of CuO-CeO2/SiC catalyst increased with calcination temperature from 800 degrees C to 900 degrees C, while decreased with calcination temperature at 900 degrees C-1000 degrees C. XRD pattern, TEM (HRTEM) images and Energy Dispersive X-ray (EDX) spectra revealed that copper-cerium composite oxides were well dispersed and immobilized on the surface of SiC grains. XRD pattern showed that the accelerated transformation of SiC crystals to amorphous SiO2 and the rapid expansion of CeO2 sub-grains at the calcination temperature of 900 degrees C-1000 degrees C, as well as the accelerated amorphization of CuO crystals at 800 degrees C-900 degrees C. The agglomeration of catalysts with sintering temperature was also proven by the BET test. At a higher calcination temperature, X-ray photoelectron spectroscopy (XPS) of Cu-2p spectra revealed the reduction of more Cu2+ in the process of SiC oxidation. According to TEM (HRTEM), XPS, and infrared radiation, the amorphous SiO2 was produced by the oxidation of superficial SiC particles, and the thickness of the SiO2 layers on SiC grains increased with the calcination temperature. A simple mechanism depicted the oxidation of CuO-CeO2/SiC was created. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.