Advanced Materials, Vol.27, No.41, 6511-6511, 2015
Designing Efficient Solar-Driven Hydrogen Evolution Photocathodes Using Semitransparent MoQ(x)Cl(y) (Q = S, Se) Catalysts on Si Micropyramids
Silicon micropyramids with n(+)pp(+) junctions are demonstrated to be efficient absorbers for integrated solar-driven hydrogen production systems enabling significant improvements in both photocurrent and onset potential. When conformally coated with MoSxCly, a catalyst that has excellent catalytic activity and high optical transparency, the highest photocurrent density for Si-based photocathodes with earth-abundant catalysts is achieved.